406179-88-2

Basic information

• Product Name: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole
• Synonyms: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole
• CAS NO: 406179-88-2
• Molecular Weight: 249.334
• Mol File: 406179-88-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole(406179-88-2)
• EPA Substance Registry System: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole(406179-88-2)

Safety Data

• Hazardous Substances Data: 406179-88-2(Hazardous Substances Data)

Upstream product

• 853688-07-0 C₁₂H₁₅NO₃S 
• 208335-94-8 N-(but-3-en-1-yl)-N-(tert-butoxycarbonyl)-4-methylbenzenesulfonamide 
• 177972-59-7 N-[(3Z)-hex-3-en-1-yl](4-methylphenyl)sulfonamide 
• 126745-58-2 1,1-dimethylethyl (Z)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate 
• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 
• 10285-80-0 N-tosyl-3-butenylamine 
• 4917-56-0 N-formyl-N-tosylamide 
• 888488-20-8 (Z)-N-(2,2-dichlorovinyl)-N-(hex-3-enyl)-p-toluenesulfonamide 
• 888488-16-2 (Z)-N-formyl-N-(hex-3-enyl)-p-toluenesulfonamide 
• 406179-98-4 N-(but-3-enyl)-N-(2,2-dichlorovinyl)-p-toluenesulfonamide 
• 205885-42-3 N-(but-3-en-1-yl)-N-ethynyl-4-methylbenzenesulfonamide 
• 888488-24-2 (Z)-N-ethynyl-N-(hex-3-enyl)-p-toluenesulfonamide 

Relevant articles and documents

Diastereoselective gold-catalyzed cycloisomerizations of Ene-ynamides

(Chemical Equation Presented) Around they go: 1,6-Ene-ynamides undergo highly diastereoselective gold-catalyzed cycloisomerizations that lead to functionalized cyclobutanones or carbonyl compounds with a 2-azabicyclo-[3.1.0] hexane subunit, depending on t

Radical cascade cyclizations and platinum(II)-catalyzed cycloisomerizations of ynamides

Ynamides are tested as new partners in radical and organometallic transformations. A radical cascade involving a 5-exo-dig cyclization followed by a 6-endo-trig radical trapping transforms ynamides into hetero-polycyclic compounds such as isoindoles, isoindolinones and pyrido-isoindolones. Various ene-tosylynamides react with platinum(II) chloride and lead to bicyclic nitrogenated heterocycles. This unprecedented and easily operated process can be coupled with a hydrolysis of the intermediate cyclic tosylenamides in a one-pot transformation, which provides cyclobutanones.

Platinum dichloride-catalyzed cycloisomerization of ene-ynamides

Various ene-tosylynamides react with platinum(II) chloride and lead to bicyclic nitrogenated heterocycles. This unprecedented and easily operated process can be coupled with a hydrolysis of the intermediate cyclic tosylenamides in a one-pot transformation