40794-89-6

Basic information

• Product Name: erythro diphenyl-1,3 trimethyl-4,6,6 heptanedione-1,5
• CAS NO: 40794-89-6
• Molecular Weight: 322.447
• Mol File: 40794-89-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: erythro diphenyl-1,3 trimethyl-4,6,6 heptanedione-1,5(CAS DataBase Reference)
• NIST Chemistry Reference: erythro diphenyl-1,3 trimethyl-4,6,6 heptanedione-1,5(40794-89-6)
• EPA Substance Registry System: erythro diphenyl-1,3 trimethyl-4,6,6 heptanedione-1,5(40794-89-6)

Safety Data

• Hazardous Substances Data: 40794-89-6(Hazardous Substances Data)

Upstream product

• 564-04-5 2,2-dimethyl-3-pentanone 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 94-41-7 benzalacetophenone 

Relevant articles and documents

ADDITION REGIOSELECTIVE D'ENOLATES DE CETONES AUX α-ENONES INFLUENCE DES FACTEURS STERIQUES SUR L'ORIENTATION ET LA REVERSIBILITE DES REACTIONS

Regio and stereochemistry in the addition of preformed magnesium and lithium ketone enolates (1 to 8) to α-enones (10 and 11) have been examined.When the substitution degree of the enolate is increased the formation of δ-diketone is favoured; neverthless a good efficiency in the synthesis of the γ-ethylenic β-ketols (1-2 addition) is obtained via bromomagnesium enolates (EMgX) under kinetic conditions.Lithium enolate (ELi) and, chiefly magnesium bienolate (E2Mg) give preferentially the Michael addition.Reversibility from 1-2 to 1-4 addition is commonly observed but the stereochemistry, if any, of the diastereoisomeric δ-diketones may be quite different when using EMgBr or E2Mg as starting enolates.