4081-14-5Relevant articles and documents
Preparation method of 2, 2'-butylidene bis(4-methyl-6-tert-butyl phenol)
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Paragraph 0029; 0030, (2017/04/28)
The invention discloses a preparation method of 2, 2'-butylidene bis(4-methyl-6-tert-butyl phenol). The preparation method includes: adding 4-methyl-6-tert-butyl phenol, sulfuric acid aqueous solution and emulsifier into a reaction kettle according to the mass ratio of 1:(1-6):(0.003-0.024), and evenly stirring; slowly dropwisely adding n-butanal, wherein the mass ratio of the 4-methyl-6-tert-butyl phenol to the n-butanal is 1:(0.2-0.4); performing reaction at 60-100 DEG C for 4-14 hours; adding organic solvent accounting for 30-200% of the volume of the solution of the third step into the solution, evenly stirring, and performing liquid separation; performing cooling and suction filtration on the upper-layer solution after the liquid separation, and drying filter cake to obtain the 2, 2'-butylidene bis(4-methyl-6-tert-butyl phenol). The preparation method has the advantages that the sulfuric acid aqueous solution and the organic solvent can be recycled, wastewater is reduced greatly, the use amount of chemical reagents is reduced greatly, production cost is lowered, high-quality 2, 2'-butylidene bis(4-methyl-6-tert-butyl phenol) can be prepared, and the method is simple to operate and suitable for large-scale industrial production.