40815-79-0

Basic information

• Product Name: 1-(2-ALLYL-3,6-DIHYDROXYPHENYL)ETHAN-1-ONE
• Synonyms: 1-(2-ALLYL-3,6-DIHYDROXYPHENYL)ETHAN-1-ONE
• CAS NO: 40815-79-0
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.21
• Mol File: 40815-79-0.mol
• Article Data: 7

Chemical Properties

• Melting Point: 107°C5
• Appearance: /
• CAS DataBase Reference: 1-(2-ALLYL-3,6-DIHYDROXYPHENYL)ETHAN-1-ONE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-ALLYL-3,6-DIHYDROXYPHENYL)ETHAN-1-ONE(40815-79-0)
• EPA Substance Registry System: 1-(2-ALLYL-3,6-DIHYDROXYPHENYL)ETHAN-1-ONE(40815-79-0)

Safety Data

• Hazardous Substances Data: 40815-79-0(Hazardous Substances Data)

Usage

Preparation

Preparation by thermal Claisen rearrangement of 5-(allyloxy)-2-hydroxyacetophenone without solvent at 200–220° (36%) or at 220–230° (74–75%).

Upstream product

• 40815-75-6 1-(5-allyloxy-2-hydroxyphenyl)-1-ethanone 
• 1125-55-9 2-Acetyl-1,4-benzoquinone 
• 762-73-2 trimethyl(allyl)stannane 
• 762-72-1 allyl-trimethyl-silane 
• 24850-33-7 allyltributylstanane 
• 490-78-8 2,5-Dihydroxyacetophenone 

Downstream Products

• 174901-52-1 2-acetyl-3-prop-2'-enyl-1,4-dimethoxybenzene 
• 1392299-35-2 1-(2-allyl-3,6-dimethoxyphenyl)-3,4-dihydroxybutan-1-one 
• 1392299-34-1 ethyl 4-[3,6-dimethoxy-2-(2-oxopropyl)phenyl]-2-hydroxy-4-oxobutanoate 
• 1392299-33-0 ethyl 4-(2-allyl-3,6-dimethoxyphenyl)-2-hydroxy-4-oxobutanoate 
• 1392299-32-9 ethyl (Z)-4-(2-allyl-3,6-dimethoxyphenyl)-2-hydroxy-4-oxobut-2-enoate 
• 1392299-38-5 1-(2-allyl-3,6-dimethoxyphenyl)-4-(tertbutyldimethylsilyloxy)-3-hydroxybutan-1-one 
• 1392299-36-3 1-(2-allyl-3,6-dimethoxyphenyl)butane-1,4-diol 
• 106627-32-1 diphenylmethyl 6-(3'-acetyl-4'-hydroxy-2'-propylphenoxy)hexanoate 
• 106627-19-4 6-(3-Acetyl-4-hydroxy-2-propyl-phenoxy)-hexanoic acid 
• 263138-75-6 1-(2-allyl-3-benzyloxy-6-methoxyphenyl)-1-ethanol 
• 263138-76-7 1-(2-allyl-6-benzyloxy-3-methoxyphenyl)-1-ethanol 
• 263138-74-5 2-allyl-6-benzyloxy-3-methoxyacetophenone 
• 263138-73-4 2-allyl-3-benzyloxy-6-methoxyacetophenone 
• 106627-41-2 2,5-dihydroxy-6-propylacetophenone 

Relevant articles and documents

Wacker oxidation methodology for the synthesis of the benzo-fused acetal core of marticin

Methodology for the synthesis of the benzo-fused acetal core of marticin is described in this paper. Condensation of readily available 1-(2-allyl-3,6- dimethoxyphenyl)ethanone with diethyl oxalate under Claisen condensation conditions furnished (Z)-ethyl

Non-catalyzed thermal reactions of acylquinones with allylstannanes

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Allylation of 2-Alkanoyl 1,4-Quinones with Allylsilanes and Allylstannanes. Efficient Synthesis of Pyranonaphthoquinone Antibiotics

Total syntheses of pyranonaphthoquinone antibiotics eleutherin, isoeleutherin, nanaomycin A, and deoxyfrenolicin are described.The crucial step in the route is a regioselective allylation of alkanoyl quinones with allylsilanes and allylstannanes.The allyl