40869-79-2

Basic information

• Product Name: [(PPh₃)₂PtH(SiHPh₂)]
• Synonyms: [(PPh₃)₂PtH(SiHPh₂)]
• CAS NO: 40869-79-2
• Molecular Weight: 903.975
• Mol File: 40869-79-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(PPh₃)₂PtH(SiHPh₂)](CAS DataBase Reference)
• NIST Chemistry Reference: [(PPh₃)₂PtH(SiHPh₂)](40869-79-2)
• EPA Substance Registry System: [(PPh₃)₂PtH(SiHPh₂)](40869-79-2)

Safety Data

• Hazardous Substances Data: 40869-79-2(Hazardous Substances Data)

Upstream product

• 1448998-03-5 bis(triphenylphosphine)(η²-2-benzoylphenylcinnamate)platinum(0) 
• 1448998-02-4 bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0) 
• 775-12-2 diphenylsilane 
• 1448998-00-2 bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenylcinnamate)platinum(0) 
• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 13517-35-6 tris(triphenylphosphine)platinum⁽⁰⁾ 

Downstream Products

• 1448998-02-4 bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0) 
• 775-12-2 diphenylsilane 

Relevant articles and documents

A new approach to light-gated Pt catalysts for the hydrosilylation

A new concept for a light-gated transition metal catalyst is presented based on a photo-active moiety in the outer ligand sphere of the complex which on irradiation reacts irreversibly with some part of the inner ligand sphere releasing a free coordination site. The principle is exemplified on a platinum complex for the hydrosilylation. It is proven that the catalytic properties of the complex and the properties of the photo-gate can be fine-tuned on the chemical problem independently of each other.