410094-59-6

Basic information

• Product Name: (E)-1-fluoro-4-(2-iodovinyl)benzene
• Synonyms: (E)-1-fluoro-4-(2-iodovinyl)benzene
• CAS NO: 410094-59-6
• Molecular Weight: 248.039
• Mol File: 410094-59-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (E)-1-fluoro-4-(2-iodovinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-fluoro-4-(2-iodovinyl)benzene(410094-59-6)
• EPA Substance Registry System: (E)-1-fluoro-4-(2-iodovinyl)benzene(410094-59-6)

Safety Data

• Hazardous Substances Data: 410094-59-6(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 459-46-1 4-Fluorobenzyl bromide 
• 352229-41-5 (E)-2-(4-fluorophenylethenyl)trimethylsilane 
• 403-42-9 1-(4-fluorophenyl)ethanone 
• 459-32-5 4-fluorocinnamic acid 
• 504433-86-7 2-[(1E)-2-(4-fluorophenyl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 214907-24-1 [2-(4-fluorophenyl)vinyl]boronic acid 

Downstream Products

• 1202656-08-3 (E)-(4-fluorostyryl)(naphthalen-2-yl)sulfane 
• 1025447-23-7 (E)-N,N-diethyl-3-(4-fluorophenyl)acrylamide 
• 39769-24-9 (E)-4-fluoro-4'-methoxystilbene 
• 504433-86-7 2-[(1E)-2-(4-fluorophenyl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 291743-95-8 2-(4-fluorophenyl)pyrazolo[1,5-a]pyridine 
• 56983-95-0 2-phenylpyrazolo[1,5-a]pyridine 
• 229467-68-9 (E)-1-fluoro-4-[2-(phenylsulfanyl)vinyl]benzene 
• 1207252-90-1 (E)-(4-fluorostyryl)(phenyl)selane 
• 410094-53-0 diethyl (2E)-1,1-difluoro-3-(4-fluorophenyl)prop-2-enylphosphonate 

Relevant articles and documents

Rhodium-Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical Investigation

The rhodium-catalyzed deoxygenation and borylation of ketones with B2pin2 have been developed, leading to efficient formation of alkenes, vinylboronates, and vinyldiboronates. These reactions feature mild reaction conditions, a broad substrate scope, and excellent functional-group compatibility. Mechanistic studies support that the ketones initially undergo a Rh-catalyzed deoxygenation to give alkenes via boron enolate intermediates, and the subsequent Rh-catalyzed dehydrogenative borylation of alkenes leads to the formation of vinylboronates and diboration products, which is also supported by density functional theory calculations.

Ruthenium-catalyzed one-pot synthesis of (E)-(2-arylvinyl)boronates through an isomerization/cross-metathesis sequence from allyl-substituted aromatics

We described the efficient preparation of (E)-(2-arylvinyl)boronates from allylbenzene derivatives on the basis of an isomerization/cross-metathesis sequence catalyzed by a modified Hoveyda-Grubbs catalyst. The implementation of the experimental procedure was simple and compatible with a large variety of substrates. This methodology provides a new chemical transformation not described to date. Allyl-substituted aromatics can thus be converted into diversely functionalized compounds, such as (E)-stilbene derivatives or (E)-vinyl azides, in only two steps. Copyright

Copper-catalyzed direct alkenylation of N-iminopyridinium ylides

(Figure Presented) A versatile Cu-catalyzed direct C-H alkenylation of N-iminopyridinium ylides, compatible with several different copper sources (including a penny), provides a powerful and inexpensive method for the synthesis of functionalized pyridine derivatives. Chemoselective functionalization of halide-containing compounds allows the synthesis of alkenyl pyridines containing reactive tethers for further functionalization