41013-43-8Relevant articles and documents
The stereospecific addition of hydroxylamines to α,β-unsaturated sulfones, nitriles and nitro compounds
O'Neil, Ian A.,Cleator, Ed,Southern, J. Mike,Bickley, Jamie F.,Tapolczay, David J.
, p. 8251 - 8254 (2001)
N-Alkyl hydroxylamines have been shown to undergo a highly stereospecific cis addition to α,β-unsaturated sulfones, nitriles and nitro compounds.
A diamine-exchange reaction of dihydropyrazines
Yamaguchi, Tadatoshi,Ito, Shigeru,Iwase, Yukiko,Watanabe, Kenji,Harano, Kazunobu
, p. 1677 - 1680 (2007/10/03)
Dihydropyrazines reacted with 1,2-diamines to form tetraazadecalins as intermediates, and then the reaction proceeded forward to dissociate into alternate dihydropyrazine and diamine, or backward to dissociate into the starting materials in certain equilibrium. The product distribution is controlled by diamine-exchange equilibrium reaction. The various equilibrium reactions were analyzed by NMR spectroscopy.