41034-83-7

Basic information

• Product Name: 3-ANTHRACEN-9-YL-PROPIONIC ACID
• Synonyms: 9-ANTHRACENEPROPIONIC ACID;3-ANTHRACEN-9-YL-PROPIONIC ACID;3-(9-Anthracenyl)propionic acid;3-(9-Anthryl)propionic acid;Anthracene-9-propanoic acid;Anthracene-9-propionic acid;3-(Anthracen-9-yl)propanoic Acid;9-Anthracenepropanoic Acid
• CAS NO: 41034-83-7
• Molecular Formula: C₁₇H₁₄O₂
• Molecular Weight: 250.29
• Mol File: 41034-83-7.mol
• Article Data: 1

Chemical Properties

• Melting Point: 193-197℃
• Boiling Point: 476.7 °C at 760 mmHg
• Flash Point: 373.3 °C
• Appearance: /
• Density: 1.241 g/cm³
• Vapor Pressure: 6.75E-10mmHg at 25°C
• Refractive Index: 1.697
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 4.59±0.10(Predicted)
• CAS DataBase Reference: 3-ANTHRACEN-9-YL-PROPIONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 3-ANTHRACEN-9-YL-PROPIONIC ACID(41034-83-7)
• EPA Substance Registry System: 3-ANTHRACEN-9-YL-PROPIONIC ACID(41034-83-7)

Safety Data

• Hazardous Substances Data: 41034-83-7(Hazardous Substances Data)

Usage

Chemical Properties

Yellow Solid

Synthesis Reference(s)

Journal of the American Chemical Society, 74, p. 4449, 1952 DOI: 10.1021/ja01137a503

InChI:InChI=1/C17H14O2/c18-17(19)10-9-16-14-7-3-1-5-12(14)11-13-6-2-4-8-15(13)16/h1-8,11H,9-10H2,(H,18,19)

Upstream product

• 122875-70-1 β-(9-Anthryl)propanoyl-m-chlorobenzoyl peroxide 

Downstream Products

• 122875-70-1 β-(9-Anthryl)propanoyl-m-chlorobenzoyl peroxide 
• 705961-52-0 3-anthracen-9-yl-N-[2-(3-[1,3]dioxan-2-ylmethyl-4-nitrophenoxy)-ethyl]-N-methyl-propionamide 
• 705961-73-5 (5-{2-[(3-anthracen-9-yl-propyl)-methylamino]-ethoxy}-indol-1-yl)-(2'-fluorobiphenyl-4-yl)-methanone 
• 705961-59-7 N-(4-{2-[(3-anthracen-9-yl-propyl)-methylamino]-ethoxy}-2-[1,3]dioxan-2-ylmethyl-phenyl)-4-bromobenzamide 
• 705961-67-7 4'-formyl-biphenyl-4-carboxylic acid N-(4-{2-[(3-anthracen-9-yl-propyl)-methylamino]-ethoxy}-2-[1,3]dioxan-2-ylmethyl-phenyl)-amide 
• 705961-77-9 (5-{2-[(3-anthracen-9-yl-propyl)-methylamino]-ethoxy}-indol-1-yl)-{4'-[(benzyl-methylamino)-methyl]-biphenyl-4-yl}-methanone 
• 705961-63-3 2'-fluoro-biphenyl-4-carboxylic acid N-(4-{2-[(3-anthracen-9-yl-propyl)-methylamino]-ethoxy}-2-[1,3]dioxan-2-ylmethyl-phenyl)-amide 
• 705961-71-3 4'-[(benzyl-methylamino)-methyl]-biphenyl-4-carboxylic acid N-(4-{2-[(3-anthracen-9-yl-propyl)-methylamino]-ethoxy}-2-[1,3]dioxan-2-ylmethyl-phenyl)amide 
• 82665-28-9 N-phenyl-3-(9-anthryl)-1-aminopropane 
• 82665-29-0 3-N-phenyl-N-<3-(9-anthryl)-1-propyl>aminopropionic acid 
• 82665-24-5 N-phenyl-N-<3-(9-anthryl)-1-propyl>-N'-methyl-N'-phenyl-1,3-diaminopropane 
• 82665-30-3 3-N-phenyl-N-<3-(9-anthryl)-1-propyl>amino-N'-methylpropionanilide 
• 82665-26-7 N-phenyl-N-<3-(9-anthryl)-1-propyl>-N'-methyl-N'-4-tolyl-1,3-diaminopropane 
• 82665-25-6 N-phenyl-N-<3-(9-anthryl)-1-propyl>-N'-methyl-N'-4-anisyl-1,3-diaminopropane 

Relevant articles and documents

On the Neophyl-like Rearrangement of 2-(9-Anthryl)ethyl Radicals

The 1,2 migration of the aryl group in deuterated 2-(9-anthryl)ethyl and 2-ethyl radicals has been studied by product analyses with the use of the competing reaction ArCH2CD2(.) + Bu3SnH.The rearrangement was so fast that equimolecular mixtures of the unrearranged (ArCH2CD2H) and rearranged (ArCD2CH3) hydrocarbons were obtained even in the presence of a large excess of Bu3SnH (ca. 1 M).The lower limit for the rate constant of the intramolecular process, kr, could be estimated as 5E7 s-1.Ab initio MO computations, performed on the2-phenylethyl radical, chosen as the simplest model for 2-arylethyls, showed that the aryl migration may occur either through the intermediacy of the spirocyclopropanecyclohexadienyl radical or via a three-membered transition state having geometrical and electronic properties different from those of the potential cyclic intermediate.The spectroscopic and chemical results are consistent with the rearrangement taking place via the intermediacy of spirocyclopropane radicals, which, as both thermochemical calculations and experimental evidence indicate, are characterized by a considerable thermodynamic stability.In fact, the spiro radicals could be easily observed by EPR spectroscopy when generated by hydrogen abstraction from the corresponding cyclic hydrocarbons, and the kinetics of their decay could be studied.The diamagnetic dimer of the 9,10-dihydro-10-spiro-9-yl radical was also isolated, and its structure determined by X-ray crystallographic analysis.The same cyclized radicals were detected when producing the two arylethyl radicals within the EPR cavity.Chemical generation of the 2-(9-anthryl)ethyl radical in the presence of low concentrations of hydrogen donors led to the isolation of remarkable amounts of the dimer of its cyclic structural isomer.These results provide evidence that the 2-anthrylethyl radical and the phenyl-substituted analogue may exist in either of the two rapidly equilibrating open-chain and cyclized forms and react preferentially in one of them depending on the experimental conditions.