41106-02-9

Basic information

• Product Name: α-(2-nitrophenyl)-N-methylnitrone
• Synonyms: α-(2-nitrophenyl)-N-methylnitrone
• CAS NO: 41106-02-9
• Molecular Weight: 180.163
• Mol File: 41106-02-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: α-(2-nitrophenyl)-N-methylnitrone(CAS DataBase Reference)
• NIST Chemistry Reference: α-(2-nitrophenyl)-N-methylnitrone(41106-02-9)
• EPA Substance Registry System: α-(2-nitrophenyl)-N-methylnitrone(41106-02-9)

Safety Data

• Hazardous Substances Data: 41106-02-9(Hazardous Substances Data)

Upstream product

• 4836-00-4 (E)-2-nitrobenzaldehyde oxime 
• 77-78-1 dimethyl sulfate 
• 4229-44-1 N-methylhydroxyamine hydrochloride 
• 552-89-6 2-nitro-benzaldehyde 
• 67-56-1 methanol 
• 6635-41-2 (Z)-2-nitrobenzaldehyde oxime 
• 124-41-4 sodium methylate 
• 74-88-4 methyl iodide 
• 56222-08-3 (2-nitrobenzyl)methylamine 

Downstream Products

• 3400-29-1 N-methyl-2-nitrobenzamide 
• 4229-44-1 N-methylhydroxyamine hydrochloride 
• 3717-25-7 2-nitrobenzaldehyde oxime 

Relevant articles and documents

Synthesis and application of phenyl Nitrone derivatives as acidic and microbial corrosion inhibitors

Nitrone has drawn great attention due to its wide applications as a 1,3-dipole in heterocyclic compounds synthesis and the bioactivities. With the special structure, nitrone can also be used as ligand in inorganic chemistry. Based on the current research,

One-pot synthesis and hydroxylaminolysis of asymmetrical acyclic nitrones

Aromatic aldehydes 1 were reductively aminated to the corresponding secondary amines 2 using NaBH4 in methanol in good yields. Amines 2 were oxidized with H2O2-WO42- regioselectively to nitrones 3, the structures of which were easily determined by reacting them with hydroxylamine hydrochloride as well as by spectral means. The products of hydroxylaminolysis in ether proved to be the corresponding benzaldehyde oximes 4 and benzyl or methyl hydroxylamine hydrochlorides 5. Copyright Taylor & Francis, Inc.

An efficient and rapid chemoselective synthesis of α-Aryl-N-methylnitrones in dry media

A simple, efficient, and eco-friendly procedure was developed for the condensation of N-methylhydroxylamine hydrochloride with benzaldehydes bearing electron-donating or electron-withdrawing substituents in the presence of powdered molecular sieves (3 A)