412041-40-8

Basic information

• Product Name: Benzene, 1,2-diethynyl-3-methyl- (9CI)
• Synonyms: Benzene, 1,2-diethynyl-3-methyl- (9CI)
• CAS NO: 412041-40-8
• Molecular Formula: C11H8
• Molecular Weight: 140.18122
• Mol File: 412041-40-8.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1,2-diethynyl-3-methyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2-diethynyl-3-methyl- (9CI)(412041-40-8)
• EPA Substance Registry System: Benzene, 1,2-diethynyl-3-methyl- (9CI)(412041-40-8)

Safety Data

• Hazardous Substances Data: 412041-40-8(Hazardous Substances Data)

Relevant articles and documents

Borylative Radical Cyclizations of Benzo[3,4]cyclodec-3-ene-1,5-diynes and N-Heterocyclic Carbene-Boranes

Borylative radical cyclization of benzo[3,4]cyclodec-3-ene-1,5-diynes to provide 5-borylated 6,7,8,9-tetrahydrobenzo[a]azulenes has been developed. The experimental results suggest that the reaction proceeds by a radical chain mechanism, in which di-tert-butyl hyponitrite (TBHN) works as a good radical initiator to form boryl radicals from N-heterocyclic carbene–boranes (NHC-boranes). The present reaction is a rare model that illustrates addition of boryl radicals to alkynes.