412274-54-5

Basic information

• Product Name: 11-(3-pentyloxiranyl)-9-undecenoic acid methyl ester
• CAS NO: 412274-54-5
• Molecular Weight: 310.477
• Mol File: 412274-54-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 11-(3-pentyloxiranyl)-9-undecenoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 11-(3-pentyloxiranyl)-9-undecenoic acid methyl ester(412274-54-5)
• EPA Substance Registry System: 11-(3-pentyloxiranyl)-9-undecenoic acid methyl ester(412274-54-5)

Safety Data

• Hazardous Substances Data: 412274-54-5(Hazardous Substances Data)

Upstream product

• 2462-85-3 linoleic acid methyl ester 

Relevant articles and documents

Selective oxidation reactions of natural compounds with hydrogen peroxide mediated by methyltrioxorhenium

We have investigated the oxidative behaviour of natural compounds such as methyl abietate (1), farnesyl acetate (2), a-ionone (3), β-ionone (4), methyl linolelaidate (5), methyl linolenate (6) and bergamottin (7) with the oxidant system methyltrioxo-rhenium/ H2O2/pyridine. The reactions, performed in CH2Cl2/H2O at 25 °C, have shown good regioand stereoselectivity. The oxidation products were isolated by HPLC or silica gel chromatography and characterized by MS(EI), 1H-, 13C-NMR, APT, gCOSY, HSQC, TOCSY and NOESY measurements. The selectivity seems to be controlled by the nucleophilicity of double bonds and by stereoelectronic and steric effects.