41231-78-1

Basic information

• Product Name: Benzenemethanol, a-methyl-a-(2-phenylethenyl)-
• CAS NO: 41231-78-1
• Molecular Formula: C16H16O
• Molecular Weight: 224.302
• Mol File: 41231-78-1.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-methyl-a-(2-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-methyl-a-(2-phenylethenyl)-(41231-78-1)
• EPA Substance Registry System: Benzenemethanol, a-methyl-a-(2-phenylethenyl)-(41231-78-1)

Safety Data

• Hazardous Substances Data: 41231-78-1(Hazardous Substances Data)

Upstream product

• 591-51-5 phenyllithium 
• 1896-62-4 (E)-benzalacetone 
• 75-24-1 trimethylaluminum 
• 94-41-7 benzalacetophenone 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 108-86-1 bromobenzene 
• 127-66-2 2-Phenyl-3-butyn-2-ol 
• 143-66-8 sodium tetraphenyl borate 
• 26138-28-3 phenylytterbium iodide 
• 75-16-1 methylmagnesium bromide 
• 917-54-4 methyllithium 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 23074-57-9 4-ethoxybut-3-en-2-one 
• 98-86-2 acetophenone 

Downstream Products

• 1636897-05-6 1-{4,5-dihydro-2,5-diphenyl-5-[ (E)-2-phenylethenyl]furan-3-yl}ethanone 
• 1354701-49-7 (E)-(3-azidobut-1-ene-1,3-diyl)dibenzene 
• 1375748-77-8 C₁₆H₁₅N₃ 
• 515-30-0 2-phenyllactic acid 
• 65-85-0 benzoic acid 
• 22360-63-0 1-Phenyl-3-methylindene 
• 22360-62-9 1-methyl-3-phenylindene 
• 109807-72-9 (+/-)-3ξ,5-diphenyl-cyclohex-4-ene-1r,2c-dicarboxylic acid-anhydride 

Relevant articles and documents

Efficient hydroarylation of terminal alkynes with sodium tetraphenylborate performed in water under mild conditions

The hydroarylation of terminal alkynes with sodium tetraphenylborate was performed in high yield within 3 h at room temperature in water, using palladium(II) complexes with imidazole ligands as catalysts. Under these conditions, differently substituted phenylacetylene substrates were converted to arylalkenes and aryl-substituted dienes. High conversion and excellent selectivity were achieved in the hydroarylation of alkynols with sodium tetraphenylborate. Only one product, arylalkene with an OH group, was formed in these reactions with the yield dependent on the kind of alkynol used. A plausible hydroarylation reaction mechanism was proposed on the basis of the palladium species identified in the reaction mixture and H/D exchange studies. The contribution of water as the hydride source was evidenced.

Synthesis, characterization, and investigations of antimicrobial activity of benzopyrans, benzofurans and spiro[4.5]decanes

In this study, the radical cyclization reactions of cyclic 1,3-dicarbonyl compounds (1a–c) and α,β-unsaturated alcohols (2a–d) through Mn(OAc)3 were performed. A series of biologically interesting dihydropyrans (3–5) and dihydrofurans (6–18) were synthesized as a result of these reactions. Spiro compounds (19–20) were obtained from the reactions of 1,3-dicarbonyl compounds and (E)-2,4-diphenyl-but-3-en-2-ol (2e). The unique structure of compound 19 was also confirmed by X-ray crystallography. In addition, the antibacterial activities of synthesized compounds were screened against some bacteria. Their zone diameters showed better results than some known antibiotics.

Catalytic Enantioselective Addition of Aryl Grignard Reagents to Ketones

We report a catalytic system for the challenging enantioselective addition of aryl Grignard reagents to ketones. Using a simple, one-pot procedure under mild conditions, a wide range of aromatic ketones are converted into diaryl alcohols in good yields and with good enantioselectivities. The catalytic enantioselective addition of aryl Grignard reagents to ketones is now possible. Using a readily available Ar-BINMOL ligand and titanium(IV) isopropoxide in a simple, one-pot procedure under mild conditions, a wide range of aromatic ketones are converted into diaryl alcohols in good yields and with good enantioselectivities.