4124-81-6

Basic information

• Product Name: methyl 7-phenyl-7-oxo-heptanoate
• Synonyms: methyl 7-phenyl-7-oxo-heptanoate
• CAS NO: 4124-81-6
• Molecular Weight: 234.295
• Mol File: 4124-81-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 7-phenyl-7-oxo-heptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 7-phenyl-7-oxo-heptanoate(4124-81-6)
• EPA Substance Registry System: methyl 7-phenyl-7-oxo-heptanoate(4124-81-6)

Safety Data

• Hazardous Substances Data: 4124-81-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 7472-43-7 6-benzoylhexanoic acid 
• 627-91-8 adipic acid monomethyl ester 
• 98-86-2 acetophenone 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 66800-56-4 N-methoxycarbonyl-6-aminohexanoic acid 
• 94803-44-8 7a-(1-pyrrolidinyl)-3-phenyl-3a,4,5,6,7,7a-hexahydro-1,2-benzoisoxazole 
• 113340-87-7 1-methoxy-3-phenyl-2-azacycloocta-1,3-diene 
• 70288-80-1 6-methoxycarbonylaminohexanoic acid methyl ester 
• 100-52-7 benzaldehyde 
• 124-41-4 sodium methylate 
• 3580-38-9 2-Benzoylcyclohexanone 

Downstream Products

• 1242279-46-4 C₂₁H₂₆N₂O₄S 
• 507278-26-4 methyl (R)-7-hydroxy-7-phenylheptanoate 

Relevant articles and documents

Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol Ethers to Synthesize Functionalized Aryl Alkyl Ketones

Photoredox-catalyzed decarboxylative alkylation of silyl enol ethers has been developed. Diverse functionalized aryl alkyl ketones were afforded in modest to good yields using N-(acyloxy)phthalimide as an easy access alkyl radical source under mild and operationally simple conditions. The excellent performance of drug molecules such as fenbufen and indomethacin and naturally occurring carboxylic acids such as stearic acid and dehydrocholic acid further demonstrated the practicability of the reaction.

Photoreactions of Benzonitrile with Cyclic Enol Ethers

Upon irradiation cyclic enol ethers such as 1-methoxy-cyclopentene (4) mainly add across the cyano group of benzonitrile (1) under formation of 2-azabutadienes of an imidoester type.This is in agreement with the so-called ΔG-correlation which was reported