4132-31-4

Basic information

• Product Name: penta‐O‐benzyl-α-D‐glucopyranoside
• Synonyms: penta‐O‐benzyl-α-D‐glucopyranoside
• CAS NO: 4132-31-4
• Molecular Weight: 630.781
• Mol File: 4132-31-4.mol
• Article Data: 41

Chemical Properties

• CAS DataBase Reference: penta‐O‐benzyl-α-D‐glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: penta‐O‐benzyl-α-D‐glucopyranoside(4132-31-4)
• EPA Substance Registry System: penta‐O‐benzyl-α-D‐glucopyranoside(4132-31-4)

Safety Data

• Hazardous Substances Data: 4132-31-4(Hazardous Substances Data)

Upstream product

• 58527-86-9 Benzyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 100-51-6 benzyl alcohol 
• 30608-21-0 1-O-trimethylsilyl-2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 492-62-6 alpha-D-glucopyranose 
• 100-39-0 benzyl bromide 
• 80300-30-7 1-O-acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 1927-62-4 tetrahydro-2-(benzyloxy)-2H-pyran 
• 53691-70-6 4,6-O-isopropylidene-D-glucopyranose 
• 2280-44-6 D-Glucose 
• 139974-84-8 phenyl 2,3,4,6-tetra-O-benzyl-1-thio-α-D-galactopyranoside 
• 90358-01-3 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl trichloroacetimidate 
• 4304-12-5 benzyl β-D-galactopyranoside 

Downstream Products

• 35094-65-6 1,6-di-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 4356-77-8 acetyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 4196-35-4 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide 
• 233674-59-4 β-2,3,4,6-tetra-O-benzyl-1-valproylglucose 
• 1420671-38-0 α-2,3,4,6-tetra-O-benzyl-1-valproylglucose 
• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 59531-24-7 2,3,4,6-tetra-O-benzyl-D-glucopyranoside 
• 85339-00-0 benzyl-6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 27851-30-5 benzyl 6-O-acetyl-2,3,4-tri-O-benzyl-β-D-gluco-pyranoside 
• 61277-58-5 ((2R,3R,4S,5R)-3,4,5,6-tetraki s(benzyloxy)tetrahydro-2H-pyran-2-yl)methanol 
• 1393113-98-8 C₃₈H₄₀O₉ 
• 6386-24-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 

Relevant articles and documents

GaCl3-catalyzed activation of alkynyl glycosides for the synthesis of O-glycosides

A catalytic amount of GaCl3 (5 mol%) was found to activate alkynyl glycosides effectively under mild reaction conditions to furnish a variety of O-glycosides in good yields with high β-selectivity. Graphical abstract: [Figure not available: see fulltext.]

Synthesis of photolabile group protected anomeric acetals and its application in carbohydrate synthesis with the assistance of continuous flow photo-reactor

Selective deprotection of photolabile anomeric 2-nitrobenzyl acetals was achieved using continuous flow photo-reactor (UV radiation at 355 nm) in methanol-water. Various protecting groups such as acetyl, benzyl, benzoyl, benzylidine, TBS, etc. were found to be highly stable during the photolysis.

N-benzoylglycine/thiourea cooperative catalyzed stereoselective O-glycosidation: Activation of O-glycosyl trichloroacetimidate donors

A new practical utility for β-stereoselective glycosylation via activation of O-glycosyl trichloroacetimidate donors using N-benzoylglycine/thiourea cooperative catalysis has been demonstrated. This method represents the first instance where amino acid derived N-benzoylglycine is used as a catalyst for O–glycosylation under mild reaction conditions at ambient temperature. NMR spectroscopy studies suggest that thiourea cocatalyst exhibit a cooperative behaviour that has a strong effect on the reaction rate, yield, and the β-selectivity.