41356-06-3

Basic information

• Product Name: 1-O-Methyl-2-O,3-O-[oxybis(phenylboranediyl)]-4-O,6-O-(phenylboranediyl)-α-D-glucopyranose
• Synonyms: (5aR,6S,7aR,11aS,11bS)-Hexahydro-6-methoxy-2,4,10-triphenyl[1,3,2]dioxaborino[4',5':5,6]pyrano[3,4-f]-1,3,5,2,4-trioxadiborepin;1-O-Methyl-2-O,3-O-[oxybis(phenylboranediyl)]-4-O,6-O-(phenylboranediyl)-α-D-glucopyranose
• CAS NO: 41356-06-3
• Molecular Formula: C25H25B3O7
• Molecular Weight: 469.8948
• Mol File: 41356-06-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-O-Methyl-2-O,3-O-[oxybis(phenylboranediyl)]-4-O,6-O-(phenylboranediyl)-α-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-Methyl-2-O,3-O-[oxybis(phenylboranediyl)]-4-O,6-O-(phenylboranediyl)-α-D-glucopyranose(41356-06-3)
• EPA Substance Registry System: 1-O-Methyl-2-O,3-O-[oxybis(phenylboranediyl)]-4-O,6-O-(phenylboranediyl)-α-D-glucopyranose(41356-06-3)

Safety Data

• Hazardous Substances Data: 41356-06-3(Hazardous Substances Data)

Upstream product

• 98-80-6 phenylboronic acid 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 3262-89-3 triphenylboroxine 
• 4056-12-6 methyl 4,6-O-(phenylborylene)-α-D-glucopyranoside 

Relevant articles and documents

Seven-membered ring boronates at trans-diol moieties of carbohydrates

MS and 1H, 13C and 11B NMR results are presented revealing the formation of cyclic seven-membered boronate structures at trans-1,2-diol moieties of carbohydrates providing new opportunities for the activation, protection and analysis of glucopyranose-based oligomers and polymers such as cellulose or starch. 'Coordination-induced shifts' in 13C NMR spectra were identified for the esterification by boronic acids of carbohydrates, which can be applied for further studies.