41447-16-9

Basic information

• Product Name: (+)-N-Methylallosedridine
• Synonyms: (+)-N-Methylallosedridine;(alphaS,2R)-alpha,1-Dimethyl-2-piperidineethanol
• CAS NO: 41447-16-9
• Molecular Formula: C9H19NO
• Molecular Weight: 157.25326
• Mol File: 41447-16-9.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (+)-N-Methylallosedridine(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-N-Methylallosedridine(41447-16-9)
• EPA Substance Registry System: (+)-N-Methylallosedridine(41447-16-9)

Safety Data

• Hazardous Substances Data: 41447-16-9(Hazardous Substances Data)

Usage

General Description

(+)-N-Methylallosedridine is a chemical compound belonging to the class of organic compounds known as isoquinoline alkaloids. These alkaloids are naturally occurring, heterocyclic compounds containing an isoquinoline moiety. (+)-N-Methylallosedridine is considered to be a weak acidic compound. It is primarily derived from certain bacteria. However, scientific literature provides limited information regarding the biological processes, toxicity, or potential applications of this specific compound. It is an area still subject to ongoing research.

Upstream product

• 190383-58-5 [2R-(2R)]-1-benzyloxycarbonyl-2-(2,3-epoxypropyl)piperidine 
• 863768-20-1 (2S,2'R)-1-[N(1')-(tert-butoxycarbonyl)piperidin-2'-yl]propan-2-ol 
• 77-78-1 dimethyl sulfate 
• 50-00-0 formaldehyd 
• 847905-90-2 3-methyl-4,6,7,8-tetrahydro-3H-pyrido[1,2-c][1,3]oxazin-1-one 
• 223477-90-5 1-tert-butoxycarboxy-2-diphenylphosphinylpiperidine 
• 175857-65-5 2-(diphenylphosphinoyl)piperidine 
• 522-33-8 Tripiperidin 
• 190383-54-1 [2R-(2R)]-1-benzyloxycarbonyl-2-(2,3-dihydroxypropyl)piperidine 
• 184535-05-5 (R)-1-benzyloxycarbonyl-2-(2-propenyl)piperidine 
• 639458-46-1 (R)-2-(2-oxo-ethyl)-piperidine-1-carboxylic acid tert-butyl ester 

Relevant articles and documents

Synthesis of bicyclic carbamates as precursors of Sedum alkaloid derivatives

Synthesis of a N-Boc-protected piperidin-2-yl phosphine oxide starting from piperidine in three steps, followed by olefination using a variety of α,β-unsaturated aldehydes resulted in tert-butyl 2-(2′- alkenylidene)piperidine-1-carboxylates in high yields

A new synthesis of all four stereoisomers of 2-(2,3- dihydroxypropyl)piperidine via iterative asymmetric dihydroxylation to cause enantiomeric enhancement. Application to asymmetric synthesis of naturally occurring piperidine-related alkaloids

Both enantiomers of 2-(2-propenyl)piperidine 1 (76-88% ee), prepared via the first asymmetric dihydroxylation (AD) of 5-hexenyl azide, underwent the second AD to provide all four of the stereoisomeric 2-(2,3- dihydroxypropyl)piperidines 2 with enantiomeric enhancement.(>98% ee). An asymmetric synthesis, starting from 2, of several 2-(2- hydroxyalkyl)piperidine alkaloids [(-)halosaline, (+)-N-methylallosedridine, (+)-8-ethylnorlobelol, (+)-sedridine, (+)-allosedridine, (-)allosedridine, and (+)-N-methylsedridine] and the ant defense alkaloids [(+)-tetraponerine-3 (T-3), T-4, T-7, and T-8] is demonstrated.

A new occurrence of di-methylisopelletierine.

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