41775-36-4Relevant articles and documents
A Chromogenic Reagent for Calcium. The Importance of Ion-pairing in Cation Selection
Mason, Andrew,Sutherland, Ian O.
, p. 1131 - 1132 (1994)
The chromoionophore 2 has been synthesized from the corresponding diaza 18-crown-6 in two steps in good overall yield, and the reagent 2 extracts calcium cations from aqueous solutions in the pH range 7-9 with moderately high selectivity as compared with
Macrocyclic Ligands with an Unprecedented Size-Selectivity Pattern for the Lanthanide Ions
Hu, Aohan,MacMillan, Samantha N.,Wilson, Justin J.
supporting information, p. 13500 - 13506 (2020/09/09)
Lanthanides (Ln3+) are critical materials used for many important applications, often in the form of coordination compounds. Tuning the thermodynamic stability of these compounds is a general concern, which is not readily achieved due to the similar coord
An Improved One-Step Method to Prepare Diaza-crown Ethers and the Cation Complexation Properties of 4,10-Diaza-18-Crown-6 with Two Transition Metal Ions
Krakowiak, Krzysztof E.,Maas, Garren E.,Bradshaw, Jerald S.,Hathaway, Jon K.,Izatt, Reed M.
, p. 179 - 182 (2007/10/02)
4,10-Diaza-15-crown-5, 4,10-diaza-18-crown-6, 4,13-diaza-21-crown-7, and 4,16-diaza-24-crown-8 were prepared by an improved method from the appropriate oligothylene glycol diiodides and diamines.The thermodynamic values of log K, ΔH and ΔS for the interaction of 4,10-diaza-18-crown-6 with Pb2+ and Ag+ were determined by a calorimetric titration method and compared with thermodynamic values for interactions of 4,13-diaza-18-crown-6 with the same cations.The thermodynamic values were found to be different for the two diaza-crown ligands. 4,10-Diaza-18-crown-6 and its 4,13-diaza-crown analog formed precipitates when treated with Co2+, Cd2+, Cu2+, and Ni2+ so that no thermodynamic data are reported for these interactions.