41780-53-4

Basic information

• Product Name: N'-(4-tert-butylcyclohexylidene)-4-Methylbenzenesulfonohydrazide
• Synonyms: N'-(4-tert-butylcyclohexylidene)-4-Methylbenzenesulfonohydrazide
• CAS NO: 41780-53-4
• Molecular Formula: C₁₇H₂₆N₂O₂S
• Molecular Weight: 322
• Mol File: 41780-53-4.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 444.7°Cat760mmHg
• Flash Point: 222.7°C
• Appearance: /
• Density: 1.14g/cm³
• CAS DataBase Reference: N'-(4-tert-butylcyclohexylidene)-4-Methylbenzenesulfonohydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: N'-(4-tert-butylcyclohexylidene)-4-Methylbenzenesulfonohydrazide(41780-53-4)
• EPA Substance Registry System: N'-(4-tert-butylcyclohexylidene)-4-Methylbenzenesulfonohydrazide(41780-53-4)

Safety Data

• Hazardous Substances Data: 41780-53-4(Hazardous Substances Data)

Usage

General Description

N'-(4-tert-butylcyclohexylidene)-4-Methylbenzenesulfonohydrazide is a chemical compound with the molecular formula C18H26N2O2S. It is commonly used as a reagent in organic synthesis and pharmaceutical research. N'-(4-tert-butylcyclohexylidene)-4-Methylbenzenesulfonohydrazide is a sulfonohydrazide derivative, which makes it useful for its hydrazine-like reactivity and ability to form covalent bonds with other molecules. Its specific structure, including the tert-butylcyclohexylidene and methylbenzenesulfonohydrazide groups, gives it unique chemical properties that make it valuable in various scientific applications. Additionally, it has potential applications in the development of new drugs and materials due to its ability to modify and functionalize other molecules.

Upstream product

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Downstream Products

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• 1379610-66-8 2-(4-(tert-butyl)cyclohexyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay

The combination of photoredox catalysis with the Wolff-Kishner (WK) reaction allows the difunctionalization of carbonyl groups by a radical-carbanion relay sequence (photo-Wolff-Kishner reaction). Photoredox initiated radical addition to N-sulfonylhydrazones yields α-functionalized carbanions following the WK-type mechanism. With sulfur-centered radicals, the carbanions are further functionalized by reaction with electrophiles including CO2 and aldehydes, whereas CF3 radical addition furnishes a wide range of gem-difluoroalkenes through β-fluoride elimination of the generated α-CF3 carbanions. More than 80 substrate examples demonstrate the broad applicability of this reaction sequence. A series of investigations including radical inhibition, deuterium labeling, fluorescence quenching, cyclic voltammetry, and control experiments support the proposed radical-carbanion relay mechanism.

Catalyst-free synthesis of spiropyrazolines from chalcones and cyclic ketone N -tosylhydrazones

Treatment of cyclic ketone N-tosylhydrazones with chalcones in the presence of cesium carbonate at 110 °C affords spiropyrazolines with high selectivity and excellent yields. This protocol possesses many advantages such as readily available and stable sta

Formal carbon insertion of n-tosylhydrazone into B-B and B-Si bonds: Gem-diborylation and gem-silylborylation of sp3 carbon

A convenient method is developed to synthesize 1,1-diboronates from the corresponding N-tosylhydrazones. This method is also applicable to synthesize 1-silyl-1-boron compounds. Meanwhile, derivatization and consecutive Pd-catalyzed cross-coupling reaction