41893-06-5Relevant articles and documents
Microbiological transformations 36: Preparative scale synthesis of chiral thioacetal and thioketal sulfoxides using whole-cell biotransformations
Alphand, Veronique,Gaggero, Nicoletta,Colonna, Stefano,Pasta, Piero,Furstoss, Roland
, p. 9695 - 9706 (1997)
This work describes the preparative scale enantioselective oxidation of some prochiral dithioacetals and dithioketals to their corresponding chiral monosulfoxides using whole-cell cultures of microorganisms.
Studies on the double alkylation of 2,2-disubstituted-1,3- dithiacycloalkane-S-oxides: Synthesis of tertiary thiol derivatives
Fuchs, Christian,Edgar, Mark,Elsegood, Mark R. J.,Weaver, George W.
, p. 21911 - 21918 (2013/11/06)
Di-alkylation of 2,2-dimethyl-1,3-dithiacycloalkane-S-oxides has been achieved allowing the synthesis of two tertiary thiol centres. The diastereoisomers of the mono-alkylated products have been shown to react at different rates. The X-ray crystal structures of three substituted dithiane-S-oxides have been determined, and the conversion of the dialkylated products into cyclic disulfide derivatives of tertiary thiols (1,2-dithiolanes) has been achieved by treatment with acid. The Royal Society of Chemistry 2013.
Stereospecific synthesis of α-lipoic acid
Menon,Kumar,Ravindranathan
, p. 5313 - 5314 (2007/10/02)
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