4196-87-6 Usage
General Description
Cream colored powder with yellow chunks.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
An ester and alcohol. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. TOXICITY - Alcohols and polyols vary widely in toxicity. Among the most toxic are methyl and allyl alcohol, which act as nervous system depressants.
Fire Hazard
Flash point data for 2-[(benzoyloxy)methyl]-2-methylpropane-1,3-diyl dibenzoate are not available. 2-[(benzoyloxy)methyl]-2-methylpropane-1,3-diyl dibenzoate is probably combustible.
Check Digit Verification of cas no
The CAS Registry Mumber 4196-87-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,1,9 and 6 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 4196-87:
(6*4)+(5*1)+(4*9)+(3*6)+(2*8)+(1*7)=106
106 % 10 = 6
So 4196-87-6 is a valid CAS Registry Number.
InChI:InChI=1/C26H24O6/c1-26(17-30-23(27)20-11-5-2-6-12-20,18-31-24(28)21-13-7-3-8-14-21)19-32-25(29)22-15-9-4-10-16-22/h2-16H,17-19H2,1H3
4196-87-6Relevant articles and documents
Molybdenum hexacarbonyl mediated alkoxycarbonylation of aryl halides
Ren, Wei,Emi,Yamane, Motoki
experimental part, p. 2303 - 2309 (2011/09/19)
Mo(CO)mediates the alkoxycarbonylation of aryl halides in their reaction with alcohols to afford arenecarboxylic acid esters. The molybdenum carbonyl complexes act as the catalyst and the source with carbon monoxide. The alkoxycarbonylation proceeds with a small excess of carbon monoxide in the form of Mo(CO)and the procedure is simple compared to the conventional method, which uses palladium catalyst under gaseous carbon monoxide. Using this procedure, a variety of carboxylic acid esters were prepared. Georg Thieme Verlag Stuttgart ? New York.