42036-73-7

Basic information

• Product Name: Benzene, (1E)-1-nonenyl-
• CAS NO: 42036-73-7
• Molecular Formula: C15H22
• Molecular Weight: 202.34
• Mol File: 42036-73-7.mol
• Article Data: 48

Chemical Properties

• CAS DataBase Reference: Benzene, (1E)-1-nonenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1E)-1-nonenyl-(42036-73-7)
• EPA Substance Registry System: Benzene, (1E)-1-nonenyl-(42036-73-7)

Safety Data

• Hazardous Substances Data: 42036-73-7(Hazardous Substances Data)

Upstream product

• 137655-39-1 (Z)-1-n-Octenylzinc bromide 
• 5292-53-5 diethyl benzalmalonate 
• 5153-67-3 nitrostyrene 
• 4282-40-0 1-Iodoheptane 
• 21369-64-2 n-hexyllithium 
• 4392-24-9 Cinnamyl bromide 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 3761-92-0 n-hexylmagnesium bromide 
• 124-13-0 Octanal 
• 110826-47-6 α-octylbenzyl benzyl ketone 
• 103-54-8 cinnamyl acetate 
• 1116-73-0 trihexylaluminium 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 100-42-5 styrene 

Downstream Products

• 1303568-37-7 C₁₇H₂₅BrO₂ 

Relevant articles and documents

Selective C-H chalcogenation of thiazoles: Via thiazol-2-yl-phosphonium salts

Thiazoles and benzothiazoles undergo regioselective C2-H chalcogenation via the sequence of thiazole C2-functionalization with phosphines to produce phosphonium salts which in turn react with S- and Se-centered nucleophiles to give products of C2-H chalco

Energy Transfer from CdS QDs to a Photogenerated Pd Complex Enhances the Rate and Selectivity of a Pd-Photocatalyzed Heck Reaction

This Article describes the design of a colloidal quantum dot (QD) photosensitizer for the Pd-photocatalyzed Heck coupling of styrene and iodocyclohexane to form 2-cyclohexylstyrene. In the presence of 0.05 mol % CdS QDs, which have an emission spectrum that overlaps the absorption spectrum of a key Pd(II)alkyl iodide intermediate, the reaction proceeds with 82% yield for the Heck product at 0.5 mol % loading of Pd catalyst; no product forms at this loading without a sensitizer. A radical trapping experiment and steady-state and transient optical spectroscopies indicate that the QDs transfer energy to a Pd(II)alkyl iodide intermediate, pushing the reaction toward a Pd(I) alkyl radical species that leads to the Heck coupled product, and suppressing undesired β-hydride elimination directly from the Pd(II)alkyl iodide. Functionalization of the surfaces of the QDs with isonicotinic acid increases the rate constant of this reaction by a factor of 2.4 by colocalizing the QD and the Pd-complex. The modularity and tunability of the QD core and surface make it a convenient and effective chromophore for this alternative mode of cooperative photocatalysis.

Stereodivergent synthesis of alkenes by controllable syn-/anti-fragmentation of β-hydroxysulfonyl intermediates

The reduction of the carbonyl group in acylated trifluoroethyl alkanesulfonates follows the Felkin-Ahn selectivity, and the so-formed diastereomeric β-hydroxysulfonyl intermediates undergo syn- and anti-fragmentation, depending on the reaction conditions. In effect, isomeric E- and Z-alkenes are formed in a stereodivergent manner, which mimics the mechanistic manifold of the Peterson olefination.