42068-12-2

Basic information

• Product Name: Silane, trimethyl(1-phenylethoxy)-, (S)-
• CAS NO: 42068-12-2
• Molecular Formula: C11H18OSi
• Molecular Weight: 194.349
• Mol File: 42068-12-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(1-phenylethoxy)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(1-phenylethoxy)-, (S)-(42068-12-2)
• EPA Substance Registry System: Silane, trimethyl(1-phenylethoxy)-, (S)-(42068-12-2)

Safety Data

• Hazardous Substances Data: 42068-12-2(Hazardous Substances Data)

Upstream product

• 14856-75-8 1-phenyl-1-trimethylsilyloxyethane 
• 98-85-1 1-Phenylethanol 
• 998-30-1 Triethoxysilane 
• 98-86-2 acetophenone 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 13735-81-4 1-styrenyloxytrimethylsilane 

Downstream Products

• 112473-31-1 [(S)-1-((S)-1-Cyclohexyl-but-3-enyloxy)-ethyl]-benzene 
• 1445-91-6 (S)-1-phenylethanol 
• 112473-33-3 C₂₁H₂₆O₂ 
• 112473-33-3 C₂₁H₂₆O₂ 
• 112473-32-2 [(S)-1-(1-Allyl-undec-10-enyloxy)-ethyl]-benzene 
• 98088-50-7 (R)-6-phenyl-4-<(S)-1-phenylmethoxy>-1-hexene 
• 98088-52-9 C₂₀H₂₄O 
• 98088-51-8 [(S)-1-((S)-1-Isopropyl-but-3-enyloxy)-ethyl]-benzene 
• 98088-53-0 [(S)-1-((R)-1-Isopropyl-but-3-enyloxy)-ethyl]-benzene 

Relevant articles and documents

Immobilization of Heteroleptic Bis(oxazoline) Zinc Catalysts on SBA-15 for Asymmetric Hydrosilylation

The C2-symmetric bis(oxazoline)s (4S,4S)-R1-BOX, with R1 = tBu and Ph, react with ZnEt2 straightforwardly to the four-coordinate complexes ((4S,4S)-R1-BOX)ZnEt2 in high yield. Their immobil

A highly enantioselective hydrogenation of silyl enol ethers catalyzed by chiral frustrated lewis pairs

Using a simple combination of tri-tert-butylphosphine and chiral borane generated in situ by the hydroboration of chiral diene with HB(C 6F5)2 as a frustrated Lewis pair catalyst, a highly enantioselective metal-free hydrogenation of silyl enol ethers was successfully realized to furnish a variety of optically active secondary alcohols in 93-99% yields with 88->99% ees.

Iron-catalysed reduction of olefins using a borohydride reagent

The iron-catalysed reduction of olefins has been achieved using a simple iron salt and sodium triethylborohydride. A wide range of mono- and trans-1,2-disubstituted alkenes have been reduced (91-100%) using 25 mol% iron(II) triflate, 1 mol% N-methyl-2-pyrrolidinone and 4 equivalents of sodium triethylborohydride. The reduction of alkynes to alkanes is also reported (up to 84%). Significantly, the reduction of trisubstituted alkenes has also been achieved (60-86%). Copyright