42088-15-3

Basic information

• Product Name: fluorine isocyanate
• Synonyms: fluorine isocyanate
• CAS NO: 42088-15-3
• Molecular Weight: 61.0155
• Mol File: 42088-15-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: fluorine isocyanate(CAS DataBase Reference)
• NIST Chemistry Reference: fluorine isocyanate(42088-15-3)
• EPA Substance Registry System: fluorine isocyanate(42088-15-3)

Safety Data

• Hazardous Substances Data: 42088-15-3(Hazardous Substances Data)

Upstream product

• 1493-04-5 HC(O)NF₂ 
• 32837-64-2 Difluoraminocarbonylisocyanat 
• 3410-77-3 tetraisocyanatosilane 
• 7782-41-4 fluorine 
• 1782-09-8 triisocyanatophosphine 
• 13709-36-9 xenon difluoride 
• 1118-02-1 trimethylsilyl isocyanate 
• 10405-27-3 difluoroamine 
• 201230-82-2 carbon monoxide 
• 13400-13-0 cesium fluoride 
• 3644-72-2 bromine isocyanate 

Downstream Products

• 13967-06-1 nitrogen monofluoride 
• 201230-82-2 carbon monoxide 

Relevant articles and documents

CFNO-Isomers - Theoretical and Experimental Studies

Geometrical parameters, relative thermodynamic stabilities, and vibrational wavenumbers have been calculated for six CFNO isomers by using various ab initio methods.The results are compared with those of the respective CHNO species.In noble gas matrices the most stable CFNO isomer fluoroisocyanate, FNCO, was prepared by photolysis of FC(O)N3 as well by the reaction FN + CO and FCN + O.The short-lived intermediate (fluorocarbonyl)nitrene, FC(O)N, formed during photolysis of FC(O)N3, was trapped as FC(O)NCO in a CO matrix.In each case the courses of the investigated matrix reactions were rationalized by identification of nearly all products and the time dependence of their formation.For the FCNO molecule a complete vibrational spectrum including 15N-, 13C-, and 18O-isotopic data was measured which enabled calculation of its general valence force field. - Key Words: Calculations, ab initio/ Fluoroisocyanate/ Matrix isolation/ Normal coordinate analysis/ Photochemistry