42091-31-6

Basic information

• Product Name: Benzamide, 2-(benzoylamino)-N-(1-methylethyl)-
• CAS NO: 42091-31-6
• Molecular Formula: C17H18N2O2
• Molecular Weight: 282.342
• Mol File: 42091-31-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzamide, 2-(benzoylamino)-N-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 2-(benzoylamino)-N-(1-methylethyl)-(42091-31-6)
• EPA Substance Registry System: Benzamide, 2-(benzoylamino)-N-(1-methylethyl)-(42091-31-6)

Safety Data

• Hazardous Substances Data: 42091-31-6(Hazardous Substances Data)

Upstream product

• 5440-69-7 N-isopropylbenzamide 
• 98-88-4 benzoyl chloride 
• 495-18-1 Benzohydroxamic acid 
• 19226-36-9 3-phenyl-5H-1,4,2-dioxazol-5-one 

Relevant articles and documents

Comparative Catalytic Activity of Group 9 [CpMIII] Complexes: Cobalt-Catalyzed C-H Amidation of Arenes with Dioxazolones as Amidating Reagents

A procedure for the [CpCoIII]-catalyzed direct C-H amidation of arenes with dioxazolone has been developed. This reaction proceeds under straightforward and mild conditions with a broad range of substrates, including anilides. A comparative study on the catalytic activity of Group 9 [{CpMCl2}2] complexes revealed the unique efficiency of the cobalt catalyst. Pick of the bunch: A variety of arenes, including anilides, underwent direct C-H amidation with dioxazolones in the presence of a cobalt catalyst with a Cp? ligand under mild and straightforward reaction conditions (see scheme; Piv=pivaloyl). A comparative study of Group 9 [CpMIII] complexes revealed the unique ability of the cobalt catalyst to promote this transformation efficiently.