42371-50-6

Basic information

• Product Name: germane, tris(2,3,4,5,6-pentafluorophenyl)-
• Synonyms: Tris(pentafluorophenyl)germane
• CAS NO: 42371-50-6
• Molecular Formula: C₁₈HF₁₅Ge
• Molecular Weight: 574.8166
• Mol File: 42371-50-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: germane, tris(2,3,4,5,6-pentafluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: germane, tris(2,3,4,5,6-pentafluorophenyl)-(42371-50-6)
• EPA Substance Registry System: germane, tris(2,3,4,5,6-pentafluorophenyl)-(42371-50-6)

Safety Data

• Hazardous Substances Data: 42371-50-6(Hazardous Substances Data)

Upstream product

• 10360-39-1 tris(pentafluorophenyl)germanium bromide 
• 344-04-7 bromopentafluorobenzene 
• 1076-44-4 pentafluorophenyl lithium 
• 60-29-7 diethyl ether 
• 1259-89-8 Chloro[tris(perfluorophenyl)]-germane 
• 59871-31-7 1,1,1,3,3,3-Hexaethyl-2,2-bis(pentafluorphenyl)trigerman 
• 69162-04-5 (C₆F₅)3GeBi(C₂H₅)2 
• 54008-40-1 bis-(pentafluoro phenyl) germane 
• 35406-49-6 bis[tris(pentafluorophenyl)germyl]mercury 
• 54008-44-5 1,1,2,2-tetrakis-(pentafluoro phenyl) digermane 

Downstream Products

• 54075-73-9 bis-{tris-(pentafluoro phenyl) germanium} zinc 
• 35406-49-6 bis[tris(pentafluorophenyl)germyl]mercury 
• 90599-62-5 C₂H₂B₁₀H₉HgGe(C₆F₅)3 
• 10177-70-5 hexakis-(pentafluoro phenyl) digermoxane 
• 1259-89-8 Chloro[tris(perfluorophenyl)]-germane 
• 54008-44-5 1,1,2,2-tetrakis-(pentafluoro phenyl) digermane 
• 54008-42-3 bis-(pentafluoro phenyl) bromo germane 
• 53378-93-1 tris-(pentafluor phenyl) methoxy germane 
• 52057-32-6 tris-(pentafluoro phenyl) (trifluoro acetoxy) germane 
• 42437-33-2 hexakis(pentafluorophenyl)digermane 
• 10177-69-2 tris-(pentafluoro phenyl) germanol 
• 69162-04-5 (C₆F₅)3GeBi(C₂H₅)2 
• 78240-47-8 (C₆F₅)3GeP(C₆H₅)Ge(C₆F₅)3 
• 59871-31-7 1,1,1,3,3,3-Hexaethyl-2,2-bis(pentafluorphenyl)trigerman 

Relevant articles and documents

donor-acceptor oligogermanes: Synthesis, structure, and electronic properties

A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these donor-acceptor oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

REACTIVITY OF THALLIUM TRIS MERCURATE

Metallic lithium and dibenzenechromium displace thallium from (R3fGe)3HgTl*1.5DME (Rf = C6F5, DME = 1,2-dimethoxyethane) to give (R3fGe)3HgLi*3DME and fGe)4Hg>2, respectively.Reactions of thallium germylmercurate with halides of metals and organometallics in DME/EtOH solution produce ionic compounds of fGe)3Hg>-M+ type, which (depending on M ) (a) may be isolated as pure compounds, (b) disproportionate, (c) form covalent derivatives R3fGe-m or (d) undergo alcoholysis.A general scheme for the reactions has been proposed.