423767-16-2

Basic information

• Product Name: (-)-menthyl (E)-2-(diethoxyphosphoryl)-3-phenylacrylate
• CAS NO: 423767-16-2
• Molecular Weight: 422.502
• Mol File: 423767-16-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-menthyl (E)-2-(diethoxyphosphoryl)-3-phenylacrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-menthyl (E)-2-(diethoxyphosphoryl)-3-phenylacrylate(423767-16-2)
• EPA Substance Registry System: (-)-menthyl (E)-2-(diethoxyphosphoryl)-3-phenylacrylate(423767-16-2)

Safety Data

• Hazardous Substances Data: 423767-16-2(Hazardous Substances Data)

Upstream product

• 16832-20-5 (1R,2S,5R)-menthol bromoacetate 
• 100-52-7 benzaldehyde 
• 141540-20-7 (diethoxy-phosphoryl)-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Relevant articles and documents

Stereochemical considerations on the stereoselective cyclopropanation reactions of 3-aryl-2-phosphonoacrylates induced by the (-)-8-phenylmenthyl group as a chiral auxiliary

The cyclopropanation of (-)-8-phenylmenthyl (E)-3-aryl-2-phosphonoacrylates E-3a-d with dimethyloxosulfonium methylide and diazomethane affords the corresponding trans cyclopropane derivatives as the major diastereomers with high diastereoselectivity. On