42536-20-9

Basic information

• Product Name: WCl(CO)2(NO)(P(C₆H₅)3)2
• CAS NO: 42536-20-9
• Molecular Weight: 829.912
• Mol File: 42536-20-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: WCl(CO)2(NO)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: WCl(CO)2(NO)(P(C₆H₅)3)2(42536-20-9)
• EPA Substance Registry System: WCl(CO)2(NO)(P(C₆H₅)3)2(42536-20-9)

Safety Data

• Hazardous Substances Data: 42536-20-9(Hazardous Substances Data)

Upstream product

• 108417-91-0 W(CH₃)(CO)2(NO)(P(C₆H₅)3)2 
• 7698-05-7 hydrogen chloride 
• 108234-41-9 [W(CO)3(NO)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[W(CO)3(NO)(P(C₆H₅)3)2]PF₆ 
• 108215-12-9 W(OClO₃)(CO)2(NO)(P(C₆H₅)3)2 

Downstream Products

• 108417-92-1 W(⁽¹³⁾CH₃)(CO)2(NO)(P(C₆H₅)3)2 
• 108417-91-0 W(CH₃)(CO)2(NO)(P(C₆H₅)3)2 
• 5158-46-3 methylzinc chloride 

Relevant articles and documents

Synthesis and reactivity of a neutral tungsten(0) alkyl complex. Insertion of CO2 into the W-CH3 bond of trans,trans-W(CH3)(CO)2(NO)(PPh3)2 and the structural characterization of trans-W(η2-O2CCH3)(CO)(NO)(PPh 3)2

Reaction of trans,trans-WCl(CO)2(NO) (PPh3)2 (1) with CH3Li or (CH3)2Zn affords trans,trans-W-(CH3)(CO)2(NO)(PPH3)2 (2) in good yields. Treatment of 2 with DCl gives 1 and CH3D quantitatively. Reaction of 2 with carbon monoxide (2 atm, 80°C) results in a reversible substitution of CO for PPh3 to give mer-W(CH3)(CO)3(NO)(PPh3) (3). Carbon dioxide undergoes a 1,2-insertion reaction with 2 to give the monodentate acetate complex trans,trans-W[η1-OC(O)CH3](CO) 2(NO)(PPh3)2 (4), which reversibly loses CO on heating to yield the bidentate acetate derivative trans-W(η2-O2CCH3)(CO)(NO)(PPh 3)2 (5). Monoclinie prisms of 5 were grown from a dichloromethane/benzene solution and crystallized in space group P21L/a with Z = 4, a = 20.864 (5) A?, b = 9.729 (2) A?, c = 17.504 (4) A?, and β = 103.21 (1)°. An X-ray diffraction study at -91 ± 3°C showed that the acetate ligand is bound in an asymmetric fashion to the tungsten center and that the nitrosyl and carbonyl ligands are not substantially disordered. Salient metrical parameters of the structure include the following: W(1)-O(4) = 2.249 (5) A?, W(1)-O(5) = 2.217 (5) A?, O(4)-C(6) = 1.270 (10) A?, O(5)-C(6) = 1.302 (10) A?, W(1)-C(8) = 1.914 (8) A?, C(8)-O(9) = 1.171 (9) A?, W(1)-N(10) = 1.836 (7) A?, N(10)-O(11) = 1.203 (9) A?, and W(1)-N(10)-O(11) = 178.3 (6)°. The least-squares refinement converged to R(F) = 0.036 and RW(F) = 0.036 for 3518 unique data with F > 3σ(F).