425369-97-7

Basic information

• Product Name: [(N-methyl-N,N-bis[3-(dimethylamino)propyl]amine)Cu^I](BAr^F₄)
• CAS NO: 425369-97-7
• Molecular Weight: 943.945
• Mol File: 425369-97-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(N-methyl-N,N-bis[3-(dimethylamino)propyl]amine)Cu^I](BAr^F₄)(CAS DataBase Reference)
• NIST Chemistry Reference: [(N-methyl-N,N-bis[3-(dimethylamino)propyl]amine)Cu^I](BAr^F₄)(425369-97-7)
• EPA Substance Registry System: [(N-methyl-N,N-bis[3-(dimethylamino)propyl]amine)Cu^I](BAr^F₄)(425369-97-7)

Safety Data

• Hazardous Substances Data: 425369-97-7(Hazardous Substances Data)

Upstream product

• 425370-02-1 tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate 
• 3855-32-1 N'-[3-(dimethylamino)propyl]-N,N,N'-trimethylpropane-1,3-diamine 

Relevant articles and documents

Dimethylanilinic N-Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper-Oxygen Species

The reaction of p-cyano-N,N-dimethylaniline N-oxide, an O-atom donor, with different copper(I) complexes (at room temperature and in acetone) indicates the formation via O-atom transfer of a high-valent copper oxyl species, CuII-O?, a putative key intermediate in the catalytic cycle of copper-containing monooxygenases. The formation of p-cyano-N-hydroxymethyl-N-methylaniline and p-cyano-N-methylaniline as the main products of the reaction highlight the capability of this species to hydroxylate strong C-H bonds (bond dissociation energy ～90 kcal/mol). A plausible mechanism for the reactivity of this catalytic system is proposed.