42738-68-1

Basic information

• Product Name: 2-ALLYLCYCLOHEXANE-1,3-DIONE
• Synonyms: 2-ALLYLCYCLOHEXANE-1,3-DIONE
• CAS NO: 42738-68-1
• Molecular Formula: C₉H₁₂O₂
• Molecular Weight: 152.19
• Mol File: 42738-68-1.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-ALLYLCYCLOHEXANE-1,3-DIONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ALLYLCYCLOHEXANE-1,3-DIONE(42738-68-1)
• EPA Substance Registry System: 2-ALLYLCYCLOHEXANE-1,3-DIONE(42738-68-1)

Safety Data

• Hazardous Substances Data: 42738-68-1(Hazardous Substances Data)

Upstream product

• 762-72-1 allyl-trimethyl-silane 
• 504-02-9 1,3-cylohexanedione 
• 591-87-7 Allyl acetate 

Downstream Products

• 54244-73-4 2-n-propyl-1,3-cyclohexanedione 
• 23438-66-6 2,2-di(prop-2-en-1-yl)cyclohexane-1,3-dione 
• 51557-84-7 2-chloro-2-allyl-1,3-cyclohexanedione 
• 84248-59-9 2-Allyl-3-pyrrolidin-1-yl-cyclohex-2-enone 
• 85696-84-0 3-methoxy-2-(propen-2-yl)cyclohex-2-en-1-one 
• 84248-63-5 2-Allyl-3-propylamino-cyclohex-2-enone 
• 1108206-36-5 2-allyl-2-(3-oxobutyl)-1,3-cyclohexanedione 
• 397251-90-0 2-((phenylselanyl)methyl)-3,5,6,7-tetrahydrobenzofuran-4(2H)-one 
• 1526921-07-2 2-allyl-2-(1-phenylprop-2-ynyl)cyclohexane-1,3-dione 
• 1401226-16-1 (S)-2-[(2-allyl-3-vinylcyclohex-2-en-1-yl)oxy]phenyl formate 
• 1401226-12-7 (S)-2-[(2-allyl-3-vinylcyclohex-2-en-1-yl)oxy]benzaldehyde 
• 1401226-11-6 (S)-2-[(2-allyl-3-vinylcyclohex-2-en-1-yl)oxy]benzonitrile 
• 1401226-07-0 (S)-2-[(2-allyl-3-vinylcyclohex-2-en-1-yl)oxy]phenol 
• 1401226-47-8 3-(1-ethoxyethenyl)-2-allyl-2-cyclohexen-1-one 

Relevant articles and documents

Solvent-controlled highly selective bis-and monoallylation of active methylene compounds by allyl acetate with palladium(0) nanoparticle

(Chemical Equation Presented) Palladium(0) nanoparticle has been used as an efficient catalyst for the allylation of active methylene compounds. Very efficient bisallylation is achieved for a variety of active methylene compounds by allyl acetate and its derivatives in one stroke in THF solvent. The reaction in water provides monoallylated product selectively by allyl acetate only. The recovered Pd(0) nanoparticle is recycled. A probable mechanism is suggested.

C-ALLYLATION OF CYCLIC β-DIKETONES IN AN ACIDIC MEDIUM WITH CATALYSIS BY Pd(0)

A method is proposed for the C-alkylation of cyclic β-diketones by allyl acetate in a weakly acidic medium with Pd(PPh3)4 as catalyst.The method makes it possible to obtain high yields of the corresponding mono- and diallylated products.