42882-50-8

Basic information

• Product Name: N-benzylidene-1-(furan-2-yl)methylamine
• Synonyms: N-benzylidene-1-(furan-2-yl)methylamine
• CAS NO: 42882-50-8
• Molecular Weight: 185.225
• Mol File: 42882-50-8.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: N-benzylidene-1-(furan-2-yl)methylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzylidene-1-(furan-2-yl)methylamine(42882-50-8)
• EPA Substance Registry System: N-benzylidene-1-(furan-2-yl)methylamine(42882-50-8)

Safety Data

• Hazardous Substances Data: 42882-50-8(Hazardous Substances Data)

Upstream product

• 617-89-0 furan-2-ylmethanamine 
• 100-52-7 benzaldehyde 
• 100-51-6 benzyl alcohol 
• 98-01-1 furfural 
• 100-46-9 benzylamine 

Downstream Products

• 847368-91-6 C₂₂H₁₅NO₄ 
• 1384131-97-8 N-benzyl-N-(furan-2-ylmethyl)benzo[d]oxazol-2-amine 
• 1403501-99-4 C₂₆H₂₄N₂O₂PbS₄ 
• 1100245-95-1 furan-2-ylmethyl-(2,2,2-trifluoro-1-phenylethyl)amine 
• 408329-67-9 [((C₅H₄N)2)NiCH(C₆H₅)N(CH₂C₄H₃O)C(O)O] 

Relevant articles and documents

α-Acylaminophosphonates possessing epoxyisoindolone moiety

α-Acylaminophosphonates possessing an epoxyisoindolone moiety were prepared with good stereoselectivity (de≥80%) by?a tandem acylation/[4+2]-cycloaddition reaction between maleic anhydride and α-aminophosphonates derived from a furfurylamine. The cycloaddition products have an opposite orientation of epoxy and phosphonate groups, which was confirmed by NMR spectroscopy and X-ray crystal structure analysis.

Sulfated polyborate: A dual catalyst for the reductive amination of aldehydes and ketones by NaBH4

An efficient, quick, and environment-friendly one-pot reductive amination of aldehydes or ketones was developed. In ethanol at 70 °C, a imination catalyzed by sulfated polyborate and further reduced by sodium borohydride yields various amines. The present method has many significant benefits, including a shorter reaction time, excellent yields, and a hassle-free, straightforward experimental process. The reaction has a wide range of applications due to its flexibility, including secondary amine for reductive amination.

Ligand-Controlled Inversion of Diastereo- and Enantioselectivity in Silver-Catalyzed Azomethine Ylide-Imine Cycloaddition of Glycine Aldimino Esters with Imines

A highly diastereo- and enantioselective silver-catalyzed azomethine ylide-imine (AYI) cycloaddition reaction of glycine aldimino esters with imines was developed in which the Xing-Phos-controlled syn-selective or DTBM-Segphos-induced anti-selective AYI cycloaddition reaction could be applied to the synthesis of a variety of stereodivergent 1-alkyl-2,5-substituted imidazolidines with high yields and excellent enantioselectivities (up to 99% ee) as well as good diastereoselectivities (up to 99:1 dr) under mild reaction conditions.