42918-26-3

Basic information

• Product Name: 3-(2,5-DIMETHYLPHENYL)-1-PROPENE
• Synonyms: 3-(2,5-DIMETHYLPHENYL)-1-PROPENE;2-Allyl-1,4-dimethylbenzene
• CAS NO: 42918-26-3
• Molecular Formula: C₁₁H₁₄
• Molecular Weight: 146.23
• Mol File: 42918-26-3.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 206.3°C at 760 mmHg
• Flash Point: 71.3°C
• Appearance: /
• Density: 0.878g/cm³
• Vapor Pressure: 0.342mmHg at 25°C
• Refractive Index: 1.51
• CAS DataBase Reference: 3-(2,5-DIMETHYLPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2,5-DIMETHYLPHENYL)-1-PROPENE(42918-26-3)
• EPA Substance Registry System: 3-(2,5-DIMETHYLPHENYL)-1-PROPENE(42918-26-3)

Safety Data

• Hazardous Substances Data: 42918-26-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H14/c1-4-5-11-8-9(2)6-7-10(11)3/h4,6-8H,1,5H2,2-3H3

Upstream product

• 106-42-3 para-xylene 
• 107-05-1 3-chloroprop-1-ene 
• 553-94-6 4-bromo-m-xylene 
• 106-95-6 allyl bromide 
• 95-87-4 2,5-Dimethylphenol 
• 95-72-7 2-chloro-1,4-dimethyl-benzene 
• 24850-33-7 allyltributylstanane 
• 762-72-1 allyl-trimethyl-silane 
• 107-18-6 allyl alcohol 
• 91-57-6 2-Methylnaphthalene 
• 827-52-1 1-phenyl-1-cyclohexane 
• 101-81-5 Diphenylmethane 
• 92-52-4 biphenyl 
• 91-20-3 naphthalene 

Relevant articles and documents

Palladium-catalyzed allylic C-H oxidation under simple operation and mild conditions

We discovered an effective and simple system (Pd/BQ/air/r.t.) for making allylic alcohols through Pd-catalyzed allylic C-H bond functionalization. This approach exhibits advantages due to its simple operation, mild conditions, and environmentally benign features. By modifying reaction conditions, it can be suitable for preparing unsaturated aldehydes, allylic esters, ethers, and amines.

Intermolecular Friedel-Crafts reaction catalyzed by InCl3

Our recent discovery that In(III) salts were able to activate halides catalytically under mild conditions for the intermolecular Friedel-Crafts cyclization prompted us to explore this highly efficient activation in intermolecular Friedel-Crafts reactions. The alkylation of p-xylene with allylic and benzylic halides was demonstrated under catalytic and mild condition to afford in some cases quantitative yields of the monoalkylated products without the need to employ large excesses of reactants.

Highly active palladium catalysts supported by bulky proazaphosphatrane ligands for stille cross-coupling: Coupling of aryl and vinyl chlorides, room temperature coupling of aryl bromides, coupling of aryl triflates, and synthesis of sterically hindered biaryls

A family of proazaphosphatrane ligands [P(RNCH2CH 2)2N(R′NCH2CH2): R = R′ = i-Bu, 1; R = Bz, R′ = 1-Bu, 3; R = R′ = Bz, 4] for palladium-catalyzed Stille reactions of aryl chlorides is described. Catalysts derived from ligands 1 and 4 efficiently catalyze the coupling of electronically diverse aryl chlorides with an array of organotin reagents. The catalyst system based on the ligand 3 is active for the synthesis of sterically hindered biaryls (di-, tri-, and tetra-ortho substituted). The use of ligand 4 allows room-temperature coupling of aryl bromides and it also permits aryl inflates and vinyl chlorides to participate in Stille coupling.