42928-43-8

Basic information

• Product Name: B-tert-butyl-9-bbn
• CAS NO: 42928-43-8
• Molecular Formula: C₁₂H₂₃B
• Molecular Weight: 178.12
• Mol File: 42928-43-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: B-tert-butyl-9-bbn(CAS DataBase Reference)
• NIST Chemistry Reference: B-tert-butyl-9-bbn(42928-43-8)
• EPA Substance Registry System: B-tert-butyl-9-bbn(42928-43-8)

Safety Data

• Hazardous Substances Data: 42928-43-8(Hazardous Substances Data)

Upstream product

• 594-19-4 tert.-butyl lithium 
• 38050-71-4 9-methoxy-9-BBN 
• 285557-42-8 9-triisopropylsilanylsulfanyl-9-bora-bicyclo[3.3.1]nonane 
• 280-64-8 9-bora-bicyclo[3.3.1]nonane 
• 38050-71-4 9-methoxy-9-borabicyclo[3.3.1]nonane 
• 74421-04-8 bis-(9-bora-bicyclo[3.3.1]non-9-yl)-amine 
• 280-64-8 9-borabicyclo[3.3.1]nonane 

Downstream Products

• 142039-30-3 (E)-1-(3,3-dimethylbut-1-en-1-yl)-4-methylbenzene 

Relevant articles and documents

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A versatile synthesis of 9-BBN derivatives from organometallic reagents and 9-(triisopropylsilyl)thio-9-borabicyclo[3.3.1]nonane

Representative B-substituted-9-BBNs (3) are efficiently prepared from either organolithium or Grignard reagents through their addition to (TIPS)S- 9-BBN (1) which is readily available from TIPSSH and 9-BBN-H. The thermally induced collapse of the intermediate 'ate' complexes (2) produces 3 which is easily isolated in good yield and high purity. (C) 2000 Elsevier Science Ltd.