43051-88-3

Basic information

• Product Name: 2,2,6-trimethyl-6-nitro-5-phenylheptan-3-one
• CAS NO: 43051-88-3
• Molecular Weight: 277.364
• Mol File: 43051-88-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2,6-trimethyl-6-nitro-5-phenylheptan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,6-trimethyl-6-nitro-5-phenylheptan-3-one(43051-88-3)
• EPA Substance Registry System: 2,2,6-trimethyl-6-nitro-5-phenylheptan-3-one(43051-88-3)

Safety Data

• Hazardous Substances Data: 43051-88-3(Hazardous Substances Data)

Upstream product

• 79-46-9 2-nitropropane 
• 538-44-3 4,4-dimethyl-1-phenyl-1-penten-3-one 
• 538-44-3 (E)-benzylidenepinacolone 
• 3958-63-2 lithium 2-nitropropane 
• 19775-91-8 (E)-4,4-dimethyl-1-phenylpent-1-en-3-ol 

Relevant articles and documents

Radical and Ionic Nucleophilic Substitution Reactions on α-Alkyl-γ-(p-nitrophenyl)allyl Derivatives

The nature of the reaction between α-alkyl-γ-(p-nitrophenyl)allyl chlorides (1)-(3), which have the general form p-O2NC6H4CH=CHCH(Cl)R, and a variety of nucleophiles depends on the alkyl group R and the nucleophile.The chloride (1) (R = Me) undergoes ionic (SN2 and subsequent Michael addition) processes with the salt (7) of 2-nitropropane to give products (15) and (16) whereas the chloride (2) (R = Pri) gives a mixture of products (17) and (18) which are shown to arise by a radical-chain nucleophilic substitution process, with allylic rearrangement-an SRN1' reaction- and ionic processes respectively.The chloride (3) (R = But) gives the SRN1' product (25) with the salt (7).Other nucleophiles with (2) and (3) appear to react by ionic (SN2 and SN2') and/or SRN1' processes; e.g. (3) gives an excellent yield of the malononitrile (32) by an SN2' process when treated with the sodium salt (9).