43084-97-5

Basic information

• Product Name: tert-butyl perester of 4-methoxybenzoic acid
• Synonyms: tert-butyl perester of 4-methoxybenzoic acid
• CAS NO: 43084-97-5
• Molecular Weight: 224.257
• Mol File: 43084-97-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: tert-butyl perester of 4-methoxybenzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl perester of 4-methoxybenzoic acid(43084-97-5)
• EPA Substance Registry System: tert-butyl perester of 4-methoxybenzoic acid(43084-97-5)

Safety Data

• Hazardous Substances Data: 43084-97-5(Hazardous Substances Data)

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 100-07-2 4-methoxy-benzoyl chloride 
• 105-13-5 4-Methoxybenzyl alcohol 
• 110-05-4 di-tert-butyl peroxide 
• 123-11-5 4-methoxy-benzaldehyde 
• 702-23-8 2-(4-Methoxyphenyl)ethanol 
• 100-09-4 4-methoxybenzoic acid 

Downstream Products

• 19207-89-7 (methylthio)methyl 4-methoxybenzoate 
• 917241-31-7 (S)-cyclohept-2-en-1-yl 4-methoxybenzoate 
• 529-33-9 1,2,3,4-Tetrahydro-1-naphthol 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 68175-34-8 1-(tert-butyl)-4-(prop-1-en-1-yl)benzene 

Relevant articles and documents

Sunlight assisted solvent free synthesis of tert-butylperesters

A green and efficient methodology has been developed for the direct conversion of aryl aldehydes to the corresponding tert-butyl peresters. The reaction has been carried out in absence of any solvent and the sunlight is used as the green source of energy. In this reaction tetrabutylammonium iodide (TBAI) acts as the mild organo catalyst and tert-butyl hydroperoxide (TBHP) serve as the source of tert-butyl group.

Bu4NI-catalyzed construction of tert-butyl peresters from alcohols

A new method for the synthesis of tert-butyl peresters directly from available alcohols catalyzed by Bu4NI at room temperature in an aqueous system was developed. Additionally, allylic esters could also be obtained by combing this method and Kharasch-Sosnovsky reaction via a two-step one-pot procedure.

Synthesis of tert-butyl peresters from aldehydes by Bu4NI- catalyzed metal-free oxidation and its combination with the Kharasch-Sosnovsky reaction

A new tert-butyl peresters synthesis directly from aldehydes and TBHP was developed via Bu4NI-catalyzed aldehyde C-H oxidation. Mechanistic studies suggest that the protocol proceeds via a radical process. Combining the method with the Kharasch-Sosnovsky reaction offers a practical approach for the synthesis of allylic esters from simple aldehydes and alkenes via a two-step one-pot procedure.