432041-90-2Relevant articles and documents
A catalyst-free one-pot construction of skeletons of 5-methoxyseselin and alloxanthoxyletin in water
Cao, Jin-Li,Shen, Su-Li,Yang, Peng,Qu, Jin
supporting information, p. 3856 - 3859 (2013/09/02)
In refluxing water and without an additional catalyst, electron-rich phenols could react with alkynoic acids or alkynoates to provide coumarin structures. The skeletons of two natural pyranocoumarins, 5-methoxyseselin and alloxanthoxyletin, could be constructed (total yield up to 76%) in an aqueous multicomponent reaction in which isoprenyl acetate, propiolic acid, and phloroglucinol were simply mixed and refluxed in water.
Mechanisms of Macrocycle Genesis. The Condensation of Resorcinol with Aldehydes
Weinelt, Frank,Schneider, Hans-Joerg
, p. 5527 - 5535 (2007/10/02)
The title reactions proceed in high yields without high dilution techniques as long as substituents allow hydrogen bonds between the phenolic units and do not lead to steric hindrance.Isomerization rates for three epimeric cyclophanes, including a hiterto