4333-55-5Relevant articles and documents
Regioselective Diboron-Mediated Semireduction of Terminal Allenes
Gates, Ashley M.,Santos, Webster L.
, p. 4619 - 4624 (2019/12/11)
A method for the regioselective reduction of the terminal double bond of 1,1-disubstituted allenes has been developed. In the presence of a palladium catalyst, tetrahydroxydiboron and stoichiometric water, allene semireduction proceeds in high yield to afford Z-alkenes selectively.
Rhodium-katalysierte Synthese dreifach substituierter Olefine aus Ethen-Derivaten und Diazoalkanen
Wolf, Justin,Brandt, Lutz,Fries, Arno,Werner, Helmut
, p. 584 - 586 (2007/10/02)
-
ARYLCYCLOPROPANE PHOTOCHEMISTRY. SUBSTITUENT EFFECTS ON THE PHOTOCHEMICAL CONVERSION OF 1,1-DIARYLCYCLOPROPANES TO 1,1-DIARYLPROPENES AND 1-ARYLINDANES.
Hixson, Stephen S.,Franke, Lothar A.
, p. 41 - 44 (2007/10/02)
The rate of photochemical rearrangement of 1,1-diarylcyclopropanes to 1,1-diarylpropenes and 1-arylindanes is enhanced by electron-withdrawing groups on the aromatic rings and diminished by electron-donating groups.