4387-46-6Relevant articles and documents
Sato,Murayama
, p. 1207 (1974)
Organocatalyzed epoxidation of alkenes in continuous flow using a multi-jet oscillating disk reactor
Spaccini, Raffaele,Liguori, Lucia,Punta, Carlo,Bj?rsvik, Hans-René
scheme or table, p. 261 - 265 (2012/05/05)
The times are changing: A batch process, the Minisci epoxidation, is transformed into a continuous-flow protocol for the selective aerobic radical epoxidation of alkenes. The use of a novel reactor type allows to considerably shorten reactor residence times. Experimental results suggest that two different reaction mechanisms exist for the oxidation: one for the batch conditions and a different one for flow synthesis protocol. Copyright
Substrate-induced diastereoselectivity in the dimethyldioxirane epoxidation of simple alkenes and dienes
Asouti,Hadjiarapoglou
, p. 1847 - 1850 (2007/10/03)
Various alkenes and dienes, such as (R)- or (S)-limonene 2, 2-carene 6, 3-carene 8, (R)-α-pinene 10, (S)-α-pinene 12, and endo-dicyclopentadiene 14 were transformed into the corresponding mono- and bis-epoxides by epoxidation with dimethyldioxirane (as an acetone solution). The selectivity observed in these epoxidations is explained by the assumption of hydrogen bonding between bridge protons and the dioxirane.