441011-26-3

Basic information

• Product Name: 3-(2'-furanyl)-2-methyl-2-cyclohexen-1-one
• Synonyms: 3-(2'-furanyl)-2-methyl-2-cyclohexen-1-one
• CAS NO: 441011-26-3
• Molecular Weight: 176.215
• Mol File: 441011-26-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(2'-furanyl)-2-methyl-2-cyclohexen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2'-furanyl)-2-methyl-2-cyclohexen-1-one(441011-26-3)
• EPA Substance Registry System: 3-(2'-furanyl)-2-methyl-2-cyclohexen-1-one(441011-26-3)

Safety Data

• Hazardous Substances Data: 441011-26-3(Hazardous Substances Data)

Upstream product

• 110-00-9 furan 
• 37457-15-1 3-isobutoxy-2-methyl-2-cyclohexen-1-one 

Downstream Products

• 441011-27-4 3-(2'-furanyl)-2-methyl-1-trimethylsiloxy-1-cyclohexene 

Relevant articles and documents

An intramolecular furan-diene diels-alder approach to 11-oxo 10α-steroids

The intramolecular cycloaddition of 14, with dimethylaluminium chloride as a catalyst and under kinetic control, yielded the exo adduct 19a. Opening of the oxygen bridge in the reduced adduct 20 gave intermediate 21. Oxidation of the latter made it possible to introduce the methyl group at C-10, which exclusively afforded 23, with the unnatural configuration. Further conversion resulted in the formation of D-homo-10-epi-adrenosterone (25). Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.