4427-28-5

Basic information

• Product Name: 1-Methylethenylamine
• Synonyms: 1-Methylethenylamine
• CAS NO: 4427-28-5
• Molecular Formula: C₃H₇N
• Molecular Weight: 57.0944
• Mol File: 4427-28-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 48.9°Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: 0.745g/cm³
• CAS DataBase Reference: 1-Methylethenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Methylethenylamine(4427-28-5)
• EPA Substance Registry System: 1-Methylethenylamine(4427-28-5)

Safety Data

• Hazardous Substances Data: 4427-28-5(Hazardous Substances Data)

Upstream product

• 77154-98-4 amino-11 methyl-11 ethano-9,10 dihydro-9,10 anthracene 

Downstream Products

• 16741-46-1 N-isopropylformamide 
• 556-72-9 2,2,4,4,6-pentamethyl-2,3,4,5,tetrahydropyrimidine 

Relevant articles and documents

REACTIONS RETRODIENIQUES-IX. SYNTHESE PAR THERMOLYSE ECLAIR ET ETUDE D'ENAMINES PRIMAIRES INSTABLES

Etheneamine 1 and its methyl derivatives 2-7 have been synthesized from the adducts 8-14 by a retro-Diels-Alder reaction under flash thermolytic conditions.The primary enamines 1-4 have been identified (IR, (1)H and (13)C NMR in a pure state at -80 deg C; at the same temperature, the enamines 5-7, less stable, are already accompanied by their tautomeric imines 33 or 34.When warmed up to room temperature, the enamines 1-7 lead, following to their substitution, either to nitrogen heterocycles (30, 42) or to acyclic azadienes (35-37, 39, 40).