444069-42-5Relevant articles and documents
Synthesis and characterization of molybdenum oxo complexes of two tripodal ligands: Reactivity studies of a functional model for molybdenum oxotransferases
Thapper, Anders,Behrens, Axel,Fryxelius, Jacob,Johansson, Maria H.,Prestopino, Fabio,Czaun, Miklos,Rehder, Dieter,Nordlander, Ebbe
, p. 3566 - 3571 (2007/10/03)
Reaction of the tetradentate ligand N-(2-hydroxybenzyl)-N,N-bis(2- pyridylmethyl)amine (L-OH) with MoO2Cl2 in methanol in the presence of NaOMe and PF6- results in the formation of [MoO2(L-O)]PF6. Similarly, the reaction of N-(2-mercaptobenzyl)-N,N-bis(2-pyridylmethyl)amine (L-SH) with MoO 2(acac)2 leads to the formation of [MoO 2(L-S)]+. The dioxo-molybdenum complex [MoO 2(L-O)]+ reacts with phosphines in methanol to afford phosphine oxides and an air-sensitive molybdenum complex, tentatively identified as [Mo(IV)O(L-O)(OCH3)]. The latter complex is capable of reducing biological oxygen donors such as DMSO or nitrate, thereby mimicking the activity of DMSO reductase and nitrate reductase. Reaction of [MoO2(L-O)] PF6 with PPh3 in other solvents than methanol leads to the formation of the Mo(V) dimer [(L-O)OMo(μ-O)MoO(L-O)](PF6) 2. The crystal structures of [MoO2(L-O)]PF6 and the μ-oxo bridged dimer are presented. The Royal Society of Chemistry 2005.
An azophenol-based chromogenic pyrophosphate sensor in water
Lee, Dong Hoon,Im, Ja Hyun,Son, Seung Uk,Chung, Young Keun,Hong, Jong-In
, p. 7752 - 7753 (2007/10/03)
A new azophenol-based colorimetric sensor shows a selective detection for pyrophosphate in aqueous solution. Copyright
