444118-41-6

Basic information

• Product Name: methyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glucopyranosiduronate
• Synonyms: methyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glucopyranosiduronate
• CAS NO: 444118-41-6
• Molecular Weight: 338.357
• Mol File: 444118-41-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glucopyranosiduronate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glucopyranosiduronate(444118-41-6)
• EPA Substance Registry System: methyl 3-O-benzyl-1,2-O-isopropylidene-α-D-glucopyranosiduronate(444118-41-6)

Safety Data

• Hazardous Substances Data: 444118-41-6(Hazardous Substances Data)

Upstream product

• 116-11-0 2-Methoxypropene 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 177897-32-4 Acetic acid (R)-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-(tert-butyl-dimethyl-silanyloxy)-ethyl ester 
• 177897-33-5 Acetic acid (R)-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-hydroxy-ethyl ester 
• 106445-04-9 1-(6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(tert-butyldimethylsiloxy)ethanol 
• 87326-73-6 (S)-methyl 2-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-hydroxyacetate 
• 87326-72-5 3-O-benzyl-1,2-O-isopropyridene-α-D-glucofuranuronic acid 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 612845-04-2 3-O-benzyl-1,2-O-isopropylidene-6-O-triisopropylsilyl-α-D-glucopyranoside 
• 210100-63-3 (3aR,5R,6R,7S,7aR)-7-Benzyloxy-5-hydroxymethyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran-6-ol 
• 2873-29-2 D-glucal triacetate 
• 356067-93-1 3-O-benzyl-6-O-triisopropylsilyl-D-glucal 

Downstream Products

• 444118-88-1 pent-4-enyl (methyl 2-O-acetyl-3-O-benzyl-4-O-tert-butyldimethylsilyl-α-L-idopyranosyluronate)-(1->4)-(6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 3-O-benzyl-2-O-levulinoyl-β-D-glucopyranosyluronate 
• 444118-91-6 6-O-acetyl-2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl-(1->4)-methyl 3-O-benzyl-2-O-levulinoyl-β-D-glucopyranosyl-(1->4)-(3,6-di-O-acetyl-2-azido-2-deoxy-α/β-D-glucopyranosyl trichloroacetimidate 
• 444118-90-5 tert-butyldimethylsilyl (6-O-acetyl-2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-(methyl 3-O-benzyl-2-O-levulinoyl-β-D-glucopyranosyl)-(1->4)-3,6-di-O-acetyl-2-azido-2-deoxy-β-D-glucopyranoside 
• 444118-89-2 pent-4-enyl (methyl 2-O-acetyl-3-O-benzyl-α-L-idopyranosyluronate)-(1->4)-(6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 3-O-benzyl-2-O-levulinoyl-β-D-glucopyranosyluronate 
• 444118-67-6 6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-methyl 2-O-levulinoyl-3-O-benzyl-α-D-glucopyranosyluronate trichloroacetimidate 
• 444118-62-1 tert-butyldimethylsilyl (6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 3-O-benzyl-2-O-levulinoyl-β-D-glucopyranosyluronate 
• 444118-69-8 6-O-acetyl-2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl-(1->4)-methyl 3-O-benzyl-2-O-levulinoyl-α-D-glucopyranosyluronate trichloroacetimidate 
• 444118-75-6 pent-4-enyl (6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 3-O-benzyl-2-O-levulinoyl-β-D-glucopyranosyluronate 
• 444118-65-4 tert-butyldimethylsilyl (6-O-acetyl-2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 3-O-benzyl-2-O-levulinoyl-β-D-glucopyranosyluronate 
• 444118-68-7 6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-methyl 2-O-allyloxycarbonyl-3-O-benzyl-α-D-glucopyranosyluronate trichloroacetimidate 
• 444118-63-2 tert-butyldimethylsilyl (6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 2-O-allyloxycarbonyl-3-O-benzyl-β-D-glucopyranosyluronate 
• 444118-60-9 6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-methyl 3-O-benzyl-2-O-monochloroacetyl-α-D-glucopyranosyluronate trichloroacetimidate 
• 444118-79-0 pent-4-enyl (6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 2-O-allyloxycarbonyl-3-O-benzyl-β-D-glucopyranosyluronate 
• 444118-64-3 tert-butyldimethylsilyl (6-O-acetyl-2-azido-3-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-methyl 3-O-benzyl-2-O-monochloroacetyl-β-D-glucopyranosyluronate 

Relevant articles and documents

Modular synthesis of heparin oligosaccharides

A general, modular strategy for the first completely stereoselective synthesis of defined heparin oligosaccharides is described. Six monosaccharide building blocks (four differentially protected glucosamines, one glucuronic and one iduronic acid) were uti

Conformational locking of the glycosyl acceptor for stereocontrol in the key step in the synthesis of heparin

Complete control over the stereoselectivity of key coupling reactions in the synthesis of heparin can be exerted by conformationally locking the uronic acid acceptor (see scheme).