446027-96-9Relevant articles and documents
Oxidative reactions of azines. 2. Synthesis and molecular structure of 3,4-dihydroxy-1-methyl-2-oxo-4-(γ-pyridyl)piperidine
Bekro,Soldatenkov,Stash,Chernikova,Chernyshev
, p. 1178 - 1181 (1996)
The oxidative ketodihydroxylation of a 1,2,3,6-tetrahydropyridine is reported. Using PMR and x-ray structural analysis, the product was shown to be 3,4-dihydroxy-1-methyl-2-oxo-4-(γ-pyridyl)piperidine. 1997 Plenum Publishing Corporation.
Oxidative reactions of azines 5.* ketodihydroxylation and coupling of 4-(γ-pyridyl)-1,2,5,6-tetrahydropyridines with acetone. Molecular and crystal structure of 3,4-dihydroxy-4-(γ-pyridyl)-1-ethylpiperidin-2-one
Soldatenkov,Bekro,Soldatova,Glover,Temesgen,Kuleshova,Khrustalev,Sergeeva
, p. 1916 - 1919 (2007/10/03)
Oxidative coupling of 1-alkyl(benzyl)-4-(γ-pyridyl)-1,2,5,6-tetrahydropyridines with acetone in the presence of KMnO4 follows two pathways and yields both 1-R-2-(acetylmethylene)tetrahydropyridines and 1-R-3,4-dihydroxypiperidin-2-ones. When ac