4485-40-9Relevant articles and documents
The X-ray crystal structure, conformation and preparation of anti-3,3,6,6-tetramethylthiepane-4,5-diol: Stereochemistry of reduction of a heterocyclic α-hydroxy ketone
Feeder, Neil,Ginnelly, Michael J.,Jones, Ray V. H.,O'Sullivan, Susan,Warren, Stuart,Wyatt, Paul
, p. 3479 - 3483 (1997)
The X-ray crystal structure and conformation of the anti title diol is described together with stereoselective syntheses of syn- and anti-diols from a readily available acyloin. Some control of the stereoselective reduction of α-hydroxy ketones by chelating and non-chelating reducing agents is possible. Copyright 1997 by the Royal Society of Chemistry.
Thiacycloalkynes for copper-free click chemistry
De Almeida, Gabriela,Sletten, Ellen M.,Nakamura, Hitomi,Palaniappan, Krishnan K.,Bertozzi, Carolyn R.
, p. 2443 - 2447 (2012/04/23)
The heteroatom helps! The introduction of an endocyclic sulfur atom enables fine-tuning of the reactivity and stability of thiacycloalkynes for copper-free click chemistry. The stabilizing effect of the endocyclic sulfur atom allows the use of highly activated seven-membered rings as reagents for bioorthogonal copper-free click chemistry. Copyright
