450408-27-2Relevant articles and documents
Daphniphyllum Alkaloids. 15. Total Syntheses of (+/-)-Methyl Homodaphniphyllate and (+/-)-Daphnilactone A
Heathcock, Clayton H.,Ruggeri, Roger B.,McClure, Kim F.
, p. 2585 - 2594 (1992)
Biomimetic total syntheses of (+/-)-daphnilactone A (6) and (+/-)-methyl homodaphniphyllate (4) have been carried out.The syntheses began with the preparation of tricyclic lactone ether 18d, which was reduced to diol 19d with LiAlH4.Oxidation of 19d gave