450412-28-9Relevant articles and documents
Phosphorus-containing bicyclic compound and preparation method and application thereof
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Paragraph 0042-0049, (2019/12/25)
The invention belongs to the technical field of electroluminescent materials, and particularly relates to a phosphorus-containing bicyclic compound and a preparation method and application thereof. The phosphorus-containing bicyclic compound has the struc
Transition-metal-free atropo-selective synthesis of biaryl compounds based on arynes
Leroux, Frédéric R.,Berthelot, Ana?s,Bonnafoux, Laurence,Panossian, Armen,Colobert, Fran?oise
supporting information, p. 14232 - 14236 (2013/01/15)
A modular way towards biaryls: Highly enantioenriched biphenyls can be prepared based on a transition-metal-free aryl-aryl coupling followed by efficient desymmetrization or deracemization and chemoselective functionalization (see scheme). Copyright
Ring opening of aziridines with ortho-bromophenyl metal reagents: synthesis of 2-substituted indolines
Michaelis, David J.,Dineen, Thomas A.
body text, p. 1920 - 1923 (2009/08/17)
Stabilized ortho-bromo phenyllithium reagents, generated via lithium-halogen exchange of aryl iodides, undergo regioselective ring opening of mono-substituted N-Boc, N-Cbz, and N-tosyl-protected aziridines in good to excellent yields. The resulting ortho-