452336-92-4

Basic information

• Product Name: 1-(tert-butyl-dimethyl-silanyloxy)-4-(2-trimethylsilanyl-ethanesulfinyl)-benzene
• Synonyms: 1-(tert-butyl-dimethyl-silanyloxy)-4-(2-trimethylsilanyl-ethanesulfinyl)-benzene
• CAS NO: 452336-92-4
• Molecular Weight: 356.677
• Mol File: 452336-92-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(tert-butyl-dimethyl-silanyloxy)-4-(2-trimethylsilanyl-ethanesulfinyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(tert-butyl-dimethyl-silanyloxy)-4-(2-trimethylsilanyl-ethanesulfinyl)-benzene(452336-92-4)
• EPA Substance Registry System: 1-(tert-butyl-dimethyl-silanyloxy)-4-(2-trimethylsilanyl-ethanesulfinyl)-benzene(452336-92-4)

Safety Data

• Hazardous Substances Data: 452336-92-4(Hazardous Substances Data)

Upstream product

• 107539-52-6 (4-((tert-butyldimethylsilyl)oxy)phenyl)magnesium bromide 
• 4206-67-1 iodo(trimethylsilyl)methane 
• 452336-90-2 tert-butyl-(4-methanesulfinyl-phenoxy)-dimethyl-silane 

Relevant articles and documents

Asymmetric conjugate addition reactions of polymer-supported highly enantioenriched β-(trimethylsilyl)ethyl sulfoxides

Optically active β-(trimethylsilyl)ethyl sulfoxides supported on Merrifield resin were treated with LDA and subsequently with methyl cinnamate at -78°C. Thermal treatment or reaction with TBAF liberated the optically active methyl 3-phenyl-5-trimethylsilylpent-4-enoate or methyl 3-phenylpent-4-enoate, respectively, in good yields with high enantioselectivity.