4551-62-6Relevant articles and documents
Abstraction of deuterium from dideuteroglycine by aryl radical: A model for 1,4-benzene diradical reactions with proteins
Braslau, Rebecca,Anderson, Marc O.
, p. 4227 - 4230 (1998)
Aryl radicals are generated by oxidation of aryl hydrazine with PbO2 or via photolysis of aryl iodide. Abstraction of deuterium from dideuteroglycine derivatives is demonstrated as a model for the possible reaction of 1,4-aryl diradicals with a
Photoinduced catalyst-free deborylation-deuteration of arylboronic acids with D2O
Lang, Yatao,Li, Chao-Jun,Peng, Xiangjun,Zeng, Huiying
supporting information, p. 6323 - 6327 (2020/11/09)
Herein, novel photoinduced catalyst-free deborylation-deuteration of arylboronic acids with D2O is reported. The protocol was compatible with a variety of functionalities, including halogen, alkoxy, cyano, sulfonyl, trimethylsilyl, trifluoromethoxy, alkyl, hydroxyl, free acid, amide, and heteroaromatic rings. A wide range of deuterated products were obtained in good yields with a high level of deuteration. This method provides a green and practical pathway to synthesize deuterium labelled compounds under mild conditions.
Continuous-flow catalytic deuterodehalogenation carried out in propylene carbonate
Orsy, Gy?rgy,Fül?p, Ferenc,Mándity, István M.
supporting information, p. 956 - 961 (2019/03/11)
A selective continuous-flow (CF) deuterodehalogenation approach is described performed in propylene carbonate, which is considered as one of the greenest solvents. Various CF technologies are known for hydrodehalogenation reactions; however, they are not