457602-58-3

Basic information

• Product Name: methyl β-phenyl-α-phenylbutyrate
• Synonyms: methyl β-phenyl-α-phenylbutyrate
• CAS NO: 457602-58-3
• Molecular Weight: 254.329
• Mol File: 457602-58-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl β-phenyl-α-phenylbutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl β-phenyl-α-phenylbutyrate(457602-58-3)
• EPA Substance Registry System: methyl β-phenyl-α-phenylbutyrate(457602-58-3)

Safety Data

• Hazardous Substances Data: 457602-58-3(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 833-81-8 1,2-diphenylpropene 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 40195-27-5 (1-methoxy-2-phenylvinyloxy)trimethylsilane 
• 672-65-1 (1-chloroethyl)benzene 
• 4013-34-7 3-phenyl-2-oxabutane 
• 585-71-7 (1-bromoethyl)benzne 
• 101-41-7 benzeneacetic acid methyl ester 

Downstream Products

• 769167-85-3 (E,4R,3'S)-3-(2',3'-diphenylbut-1'-enyl)-4-isopropyloxazolidin-2-one 
• 769167-84-2 (E,4R,3'R)-3-(2',3'-diphenylbut-1'-enyl)-4-isopropyloxazolidin-2-one 
• 457602-65-2 (4R,3'S,4'S,1''S)-4-methyl-3-[4'-phenyl-4'-(1''-phenylethyl)[1',2']dioxetan-3'-yl]oxazolidin-2-one 
• 457602-68-5 (R)-3-((1S,2S,3R)-1,2-Dihydroxy-2,3-diphenyl-butyl)-4-isopropyl-oxazolidin-2-one 
• 677032-07-4 4(R)-isopropyl-3-[(3S,4S)-4-phenyl-4-S-(1-phenylethyl)-[1,2]-dioxetan-3-yl]oxazolidin-2-one 
• 457602-66-3 4(R)-isopropyl-3-[(3S,4S)-4-phenyl-4-R-(1-phenylethyl)-[1,2]-dioxetan-3-yl]oxazolidin-2-one 
• 457602-59-4 2,3-diphenylbutyraldehyde 
• 904848-89-1 (E)-(R)-N-[(3S)-2,3-diphenylbut-1-enyl]-4-methyloxazolidin-2-one 
• 108774-24-9 2,3-diphenyl-1-butanol 

Relevant articles and documents

Highly diastereoselective dioxetane formation in the photooxygenation of enecarbamates with an oxazolidinone chiral auxiliary: Steric control in the [2 + 2] cycloaddition of singlet oxygen through conformational alignment

The photooxygenation of oxazolidinone-substituted enecarbamates leads to diastereomerically pure dioxetanes. The high diastereoselectivity is rationalized in terms of effective π-facial control achieved by shielding one side of the double bond with the ch

Indium-catalyzed coupling reaction between silyl enolates and alkyl chlorides or alkyl ethers

The coupling reactions of alkyl chlorides with silyl enolates catalyzed by InBr3, and the coupling reactions of alkyl ethers with silyl enolates catalyzed by the combined Lewis acid of InBr3/Me3SiBr are described. In both reaction systems, various types of silyl enolates were used to give corresponding α-alkylated esters, ketones, carboxylic acids, amides, thioesters, and aldehydes.