459868-12-3

Basic information

• Product Name: C₄₀H₃₅ClOP₂Pd
• CAS NO: 459868-12-3
• Molecular Weight: 735.538
• Mol File: 459868-12-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₄₀H₃₅ClOP₂Pd(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₀H₃₅ClOP₂Pd(459868-12-3)
• EPA Substance Registry System: C₄₀H₃₅ClOP₂Pd(459868-12-3)

Safety Data

• Hazardous Substances Data: 459868-12-3(Hazardous Substances Data)

Upstream product

• 161265-03-8 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene 

Relevant articles and documents

Application of Methyl Bisphosphine-Ligated Palladium Complexes for Low Pressure N-11C-Acetylation of Peptides

A mild and effective method is described for 11C-labeling of peptides selectively at the N-terminal nitrogen or at internal lysine positions. The presented method relies on the use of specific biphosphine palladium–methyl complexes and their high reactivity towards amino-carbonylation of amine groups in the presence [11C]carbon monoxide. The protocol facilitates the production of native N-11C-acetylated peptides, without any structural modifications and has been applied to a selection of bioactive peptides.