463945-93-9

Basic information

• Product Name: [(C₅H₅)(CO)(P(C₆H₅)3)Fe(N₄CC₆H₄CN)]
• CAS NO: 463945-93-9
• Molecular Weight: 581.396
• Mol File: 463945-93-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(C₅H₅)(CO)(P(C₆H₅)3)Fe(N₄CC₆H₄CN)](CAS DataBase Reference)
• NIST Chemistry Reference: [(C₅H₅)(CO)(P(C₆H₅)3)Fe(N₄CC₆H₄CN)](463945-93-9)
• EPA Substance Registry System: [(C₅H₅)(CO)(P(C₆H₅)3)Fe(N₄CC₆H₄CN)](463945-93-9)

Safety Data

• Hazardous Substances Data: 463945-93-9(Hazardous Substances Data)

Upstream product

• 14389-10-7 5-(4-cyanophenyl)tetrazole 
• 463945-72-4 [(C₅H₅)(CO)(P(C₆H₅)3)Fe(C₄H₈O)]⁽¹⁺⁾*O₃SCF₃^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C₄H₈O)](O₃SCF₃) 
• 463945-79-1 [(cyclopentadienyl)Fe(CO)(triphenylphosphine)(1,4-dicyanobenzene)](CF₃SO₃) 

Downstream Products

• 463946-00-1 C₅H₅Fe(CO)(P(C₆H₅)3)(CH₃N₄CC₆H₄CN)⁽¹⁺⁾*CF₃O₂SO^(1-)=[C₅H₅Fe(CO)(P(C₆H₅)3)(CH₃N₄CC₆H₄CN)](CF₃O₂SO) 

Relevant articles and documents

Synthesis and NMR characterization of dinuclear Fe(II) organometallic complexes containing a non-equivalently bridging 5-aryl tetrazolate ligand

The synthetic routes to the formation of a wide range of dinuclear Fe(II) organometallic complexes of the general formula [Cp(CO)(L)Fe-N 4C-C6H4-CN-Fe(L)(CO)Cp][SO3CF 3], in which the 4-cyanophenyl-tetrazolate anion N 4C-C6H4-CN acts as bridging ligand, are described. 1H and 13C NMR characterization of the product complexes indicate the presence of a significant interannular conjugation effect involving the aromatic rings of the organic spacer, the extent of which can be chemically modified by addition of electrophiles such as CH3+ and H+. Furthermore, the reversibility of protonation reaction entails the opportunity of modulating the conjugative properties of the title compounds by a proton addition-elimination mechanism.